{"id":"W4317777177","doi":"10.1039/d2cc06681e","title":"Breaking bonds and breaking rules: inert-bond activation by [( <sup>i</sup> Pr <sub>3</sub> P)Ni] <sub>5</sub> H <sub>4</sub> and catalytic stereospecific norbornene dimerization","year":2023,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Norbornene; Stereospecificity; Catalysis; Inert; Chemistry; Medicinal chemistry; Crystallography; Photochemistry; Organic chemistry; Polymerization; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002980983,0.0002970681,0.0002522618,0.0001254846,0.0004589812,0.0009942562,0.0008969432,0.000801086,0.00642394],"category_scores_gemma":[0.0007465986,0.000302612,0.0002458064,0.0001114456,0.001045754,0.002185812,0.0005546189,0.001415581,0.0009665332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004124866,"about_ca_system_score_gemma":0.0002601371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006874085,"about_ca_topic_score_gemma":0.001110592,"domain_scores_codex":[0.9997812,0.00002546828,0.00001203369,0.00005843824,0.00005499223,0.00006797702],"domain_scores_gemma":[0.9998852,0.00002461486,0.00001608943,0.00004461326,0.00001023245,0.00001917662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001901127,0.0004230839,0.00224514,0.0006747696,0.0001418572,0.001632079,0.001083664,0.002689022,0.598646,0.3112216,0.007831294,0.07151034],"study_design_scores_gemma":[0.0001683426,0.0007649797,0.00219065,0.00005094729,0.00006807976,0.00104248,0.001474826,0.00532896,0.7914854,0.1505424,0.04677998,0.0001028984],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9272445,0.003418782,0.0143871,0.004152603,0.0009442796,0.00007786355,0.0002195982,0.0006164524,0.04893873],"genre_scores_gemma":[0.9914109,0.0004817654,0.001555288,0.000258594,0.00001636527,0.00001372572,0.0001118608,0.00006231122,0.006089301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00642394,"threshold_uncertainty_score":0.02149028,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01982433063740422,"score_gpt":0.2317094502526801,"score_spread":0.2118851196152759,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}