{"id":"W4317904071","doi":"10.1002/slct.202300057","title":"Carbon‐Carbon Bond Formation “Catalyzed” by Ion‐Pair Constituents","year":2023,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ontario Tech University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Counterion; Halide; Molecule; Ionic bonding; Halocarbon; Alkali metal; Chemical physics; Ion; Photochemistry; Computational chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001130558,0.0003704039,0.0003052127,0.0001656463,0.0006084011,0.000481023,0.0005808771,0.0004557823,0.004636495],"category_scores_gemma":[0.0002264616,0.0002021657,0.0003020868,0.0001680325,0.0004256037,0.0004078994,0.0002924747,0.0002844363,0.0003842826],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004882311,"about_ca_system_score_gemma":0.0004691972,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002091049,"about_ca_topic_score_gemma":0.00168496,"domain_scores_codex":[0.99993,0.0000122214,0.000001433395,0.0000140009,0.00002180962,0.00002055835],"domain_scores_gemma":[0.9999439,0.00002224297,0.000008924996,0.00001036954,0.000006889498,0.000007707473],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000553234,0.0002893033,0.004062813,0.0006021189,0.0001363014,0.000925319,0.0006094751,0.7023903,0.2280707,0.04198039,0.001147271,0.01923273],"study_design_scores_gemma":[0.000100308,0.0004011105,0.001562175,0.00001441522,0.00005577593,0.000214777,0.000151186,0.8148955,0.1732101,0.005236886,0.004124739,0.00003294334],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9707441,0.000195908,0.01353583,0.00009458524,0.00003399705,0.00004406205,0.0001239896,0.0001447707,0.01508279],"genre_scores_gemma":[0.9957617,0.00009937759,0.002756524,0.000009554829,0.000002221049,0.00001925389,0.00005140653,0.00002324883,0.001276628],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004636495,"threshold_uncertainty_score":0.01551062,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01109838150924904,"score_gpt":0.2501309886731083,"score_spread":0.2390326071638593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}