{"id":"W4317914929","doi":"10.26434/chemrxiv-2023-lrg06","title":"Competitive Isomerization and Catalyst Decomposition During Ring-Closing Metathesis","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Isomerization; Catalysis; Chemistry; Yield (engineering); Carbene; Metathesis; Salt metathesis reaction; Electrospray ionization; Photochemistry; Combinatorial chemistry; Organic chemistry; Ion; Materials science; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003814993,0.0004430472,0.0003683188,0.0002074004,0.0001851804,0.0005326954,0.00047555,0.0004841919,0.002128244],"category_scores_gemma":[0.0007268917,0.0002913637,0.0002699647,0.0002007766,0.0003996055,0.0007482354,0.0003254033,0.0009674265,0.0004635677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004175497,"about_ca_system_score_gemma":0.0001814729,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003133983,"about_ca_topic_score_gemma":0.0003852309,"domain_scores_codex":[0.9995938,0.00004010256,0.00001354887,0.0001412498,0.0001057845,0.0001054637],"domain_scores_gemma":[0.9998015,0.00008536956,0.0000464531,0.00002951846,0.00001716649,0.00002006189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001755895,0.00002462816,0.0003981742,0.00006145927,0.00001422345,0.000142528,0.0000771333,0.0004583587,0.9942262,0.0008343699,0.0001035948,0.00348382],"study_design_scores_gemma":[0.000006510527,0.00007509492,0.0005515202,0.000002194445,0.000003773862,0.00008113381,0.0000150532,0.001950595,0.996641,0.0001310597,0.0005376321,0.000004342512],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9873183,0.0008894312,0.007930094,0.0001177679,0.00003242623,0.00004051064,0.0002358643,0.0002117261,0.003223777],"genre_scores_gemma":[0.9969403,0.0002826077,0.001754034,0.00004019192,0.000007775198,0.00001616356,0.000111722,0.00004565591,0.0008017704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002128244,"threshold_uncertainty_score":0.007119656,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02713190688753729,"score_gpt":0.2965302659465006,"score_spread":0.2693983590589633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}