{"id":"W4317914929","doi":"10.26434/chemrxiv-2023-lrg06","title":"Competitive Isomerization and Catalyst Decomposition During Ring-Closing Metathesis","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Isomerization; Catalysis; Chemistry; Yield (engineering); Carbene; Metathesis; Salt metathesis reaction; Electrospray ionization; Photochemistry; Combinatorial chemistry; Organic chemistry; Ion; Materials science; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002843295,0.0004729905,0.0005989156,0.00009871015,0.0001838879,0.0001496508,0.0003274643,0.0004871041,0.0004517646],"category_scores_gemma":[0.0003983108,0.0005609749,0.0001761061,0.0001598185,0.0001547344,0.00006766332,0.0008875249,0.0006203635,0.00004353899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002762344,"about_ca_system_score_gemma":0.00006895529,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003309444,"about_ca_topic_score_gemma":0.000003404844,"domain_scores_codex":[0.9978397,0.00004378881,0.0004929837,0.0009756245,0.000292311,0.0003555611],"domain_scores_gemma":[0.9982791,0.0003357249,0.0003758134,0.0007678622,0.00008780537,0.0001537114],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001724729,0.00004226799,0.0005592481,0.001872951,0.0002216246,0.00001943102,0.0004084588,0.00002775801,0.9960695,0.00006907996,0.00001129535,0.000681144],"study_design_scores_gemma":[0.000335137,0.00000194048,0.001532403,0.0008492091,0.0002956156,0.00004733244,0.0003593033,0.0004482174,0.9948243,0.0005874116,0.0001868235,0.000532245],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885548,0.0003875628,0.0008177454,0.0002805493,0.0002614876,0.0001215029,0.00003797449,0.0005871438,0.008951287],"genre_scores_gemma":[0.9913812,0.0002616169,0.006139981,0.00001346662,0.0003828663,0.00007452781,0.000392379,0.0001646371,0.001189371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007761916,"threshold_uncertainty_score":0.9996842,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02713190688753729,"score_gpt":0.2965302659465006,"score_spread":0.2693983590589633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}