{"id":"W4318753536","doi":"10.1039/d2cc06744g","title":"B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-catalyzed cyclopropanation of 3-alkenyl-oxindoles with diazomethanes","year":2023,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Ningbo University","keywords":"Cyclopropanation; Oxindole; Catalysis; Chemistry; Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005353783,0.0007477312,0.0009230028,0.0004787778,0.0005284164,0.0001193844,0.002229369,0.0006501159,0.00002197418],"category_scores_gemma":[0.0008260055,0.0007702204,0.0004139206,0.002063469,0.0007739636,0.0004428265,0.001220478,0.001423019,0.0004475639],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005143023,"about_ca_system_score_gemma":0.0003166717,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003997646,"about_ca_topic_score_gemma":0.0001341111,"domain_scores_codex":[0.9955898,0.000187552,0.001282941,0.0009784097,0.001074501,0.0008867807],"domain_scores_gemma":[0.9924695,0.001158529,0.0008715663,0.004308123,0.0007620326,0.0004301981],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001147871,0.0004441685,0.0002448153,0.0004139032,0.0002068076,0.000008430163,0.0006330829,0.00002809054,0.9774648,0.0006909812,0.0003019198,0.0194482],"study_design_scores_gemma":[0.001448558,0.0000346568,0.0006540002,0.000360459,0.0002831601,0.00006476456,0.001321989,0.0005908217,0.9922183,0.001285172,0.0008946792,0.0008434099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993526,0.0006123022,0.0002819121,0.0009693523,0.0001129182,0.000586362,0.0002247653,0.001023862,0.002662545],"genre_scores_gemma":[0.9918567,0.002731941,0.0009750353,0.00007049815,0.0001973261,0.0006560346,0.003257402,0.0002251376,0.00002991746],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01860479,"threshold_uncertainty_score":0.9994749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02342663567489143,"score_gpt":0.2537750736109952,"score_spread":0.2303484379361038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}