{"id":"W4318955894","doi":"10.1016/j.jelechem.2023.117220","title":"Absolute quantum efficiencies for electrochemiluminescence and chemiluminescence of protoporphyrin IX dimethyl ester","year":2023,"lang":"en","type":"article","venue":"Journal of Electroanalytical Chemistry","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Collaborative Innovation Center of Suzhou Nano Science and Technology; Natural Science Foundation of Hunan Province; Priority Academic Program Development of Jiangsu Higher Education Institutions; China Scholarship Council; Western University; National Natural Science Foundation of China","keywords":"Chemistry; Electrochemiluminescence; Chemiluminescence; Protoporphyrin IX; Photochemistry; Organic chemistry; Chromatography; Detection limit; Photodynamic therapy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004418833,0.0002094287,0.0004175747,0.00007601979,0.00005221211,0.00001802575,0.000262778,0.0001830266,0.000001665969],"category_scores_gemma":[0.0007162885,0.0001712924,0.0002661723,0.000398368,0.0002631831,0.000009046094,0.00007608574,0.000190122,2.625108e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002074546,"about_ca_system_score_gemma":0.0001291778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":8.504214e-7,"about_ca_topic_score_gemma":4.586166e-7,"domain_scores_codex":[0.9984547,0.0000153737,0.0005824865,0.0003010967,0.0002631223,0.0003832337],"domain_scores_gemma":[0.9986664,0.00007271989,0.0004184188,0.000244413,0.0004708727,0.0001271567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002236061,0.00006292164,0.0002735547,0.0001446792,0.000107355,0.000004749672,0.000007805468,0.000003092332,0.998,0.00002262545,0.0007418106,0.0004078326],"study_design_scores_gemma":[0.0003676386,0.0004107848,0.0002305409,0.00005998001,0.0001312315,0.0001253447,0.00003753905,0.0006804201,0.9964501,0.0003182098,0.0009971573,0.0001910751],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959595,0.0004832296,0.002897697,0.0002937018,0.00001752177,0.000208044,0.000008345054,0.00001983254,0.0001121322],"genre_scores_gemma":[0.9964659,0.0003391414,0.002419109,0.00004288603,0.0002196969,0.00001314923,0.00001905303,0.00002058248,0.0004604949],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001549889,"threshold_uncertainty_score":0.69851,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01017194440072674,"score_gpt":0.2816352457269697,"score_spread":0.271463301326243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}