{"id":"W4319825921","doi":"10.1021/acs.langmuir.2c03391","title":"Elucidation of an Aggregate Excited State in the Electrochemiluminescence and Chemiluminescence of a Thermally Activated Delayed Fluorescence (TADF) Emitter","year":2023,"lang":"en","type":"article","venue":"Langmuir","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; H2020 Marie Skłodowska-Curie Actions; Western University; Canada Foundation for Innovation","keywords":"Electrochemiluminescence; Chemiluminescence; Excited state; Common emitter; Fluorescence; Chemistry; Photochemistry; Luminescence; Excimer; Quantum yield; Electrochemistry; Analytical Chemistry (journal); Physical chemistry; Materials science; Electrode; Optoelectronics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001853325,0.0001900578,0.0001424264,0.0001397208,0.0001031056,0.0002955339,0.0002823499,0.0002751757,0.0007403535],"category_scores_gemma":[0.0002196742,0.0001225328,0.0001517837,0.00009787497,0.0001738674,0.0003435796,0.0001249297,0.0004498522,0.0001946334],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002522452,"about_ca_system_score_gemma":0.0001308617,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003277061,"about_ca_topic_score_gemma":0.0003064394,"domain_scores_codex":[0.9999177,0.00001026423,0.000004314973,0.00003072899,0.00002236733,0.00001455938],"domain_scores_gemma":[0.9999015,0.00003504445,0.00002175403,0.000008337188,0.00002038498,0.00001293423],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001144276,0.000002797243,0.00006067612,0.000005733422,7.495495e-7,0.00001538829,0.00000752523,0.00002610914,0.9994191,0.00006566574,0.00000573194,0.0003790569],"study_design_scores_gemma":[0.000001744338,0.00002822174,0.0007536523,6.742407e-7,0.00000216317,0.00005227384,0.000006537449,0.0007862309,0.998105,0.0000209854,0.0002411822,0.000001227593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9684681,0.000418848,0.02949936,0.00006662679,0.00000638708,0.00001966889,0.0001206278,0.00009763569,0.001302823],"genre_scores_gemma":[0.985091,0.0002609135,0.01253757,0.00002614179,0.000004394447,0.00003157223,0.0001765329,0.00002261439,0.001849286],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007403535,"threshold_uncertainty_score":0.002476692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007419744037378262,"score_gpt":0.2591270438547379,"score_spread":0.2517072998173596,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}