{"id":"W4319843513","doi":"10.1002/ange.202218587","title":"Frustrated Lewis Pair Adduct of Atomic P(−1) as a Source of Phosphinidenes (PR), Diphosphorus (P<sub>2</sub>), and Indium Phosphide","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphinidene; Adduct; Frustrated Lewis pair; Chemistry; Phosphide; Lewis acids and bases; Thermal decomposition; Intramolecular force; Indium phosphide; Tin; Indium; Phosphorus; Medicinal chemistry; Inorganic chemistry; Stereochemistry; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006236978,0.0002111857,0.0001421766,0.00008242828,0.0001494507,0.0001856336,0.0002371518,0.000168837,0.001257076],"category_scores_gemma":[0.0001365592,0.00009415334,0.00006393087,0.00009179043,0.000195582,0.0001743936,0.0003745701,0.0002231362,0.0001651275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001763603,"about_ca_system_score_gemma":0.00008251911,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002589078,"about_ca_topic_score_gemma":0.0003880543,"domain_scores_codex":[0.9999442,0.00001097448,0.000002445837,0.00001196431,0.00001520683,0.00001511488],"domain_scores_gemma":[0.9999372,0.000009486803,0.00002299743,0.00001212707,0.000006836744,0.0000113708],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001615801,0.0000205035,0.0004319153,0.00007902628,0.00002442383,0.0002027354,0.0001075952,0.0004638099,0.9952621,0.001009692,0.0002053447,0.00203119],"study_design_scores_gemma":[0.00001525144,0.0002276336,0.0006450202,0.000001782171,0.00001060914,0.0001653117,0.0000239177,0.0009353645,0.9964342,0.00007519901,0.001460282,0.000005458266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976963,0.00008421771,0.0009475139,0.00002080307,0.000006295629,0.000004544095,0.00002657833,0.00004125915,0.001172483],"genre_scores_gemma":[0.998823,0.00004026429,0.0004231204,0.000009791494,0.00000263018,0.000003465387,0.00003002719,0.000009390246,0.0006582775],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001257076,"threshold_uncertainty_score":0.004205287,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01073243599049251,"score_gpt":0.222665314426697,"score_spread":0.2119328784362045,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}