{"id":"W4319940294","doi":"10.1021/acscatal.2c06168","title":"Rapid Aerial Oxidation of Ruthenium-Dithiocatecholate Catalysts: A Challenge to Stereoretentive Olefin Metathesis","year":2023,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Ruthenium; Catalysis; Metathesis; Chemistry; Nucleophile; Olefin metathesis; Ligand (biochemistry); Amine gas treating; Olefin fiber; Salt metathesis reaction; Combinatorial chemistry; Reactivity (psychology); Medicinal chemistry; Organic chemistry; Photochemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002422747,0.0002585442,0.0002109496,0.0001229014,0.00009057832,0.0003973305,0.0003044516,0.000378199,0.0009067005],"category_scores_gemma":[0.0003041481,0.0001527295,0.0001340207,0.00008258902,0.0002149974,0.0003825298,0.000267619,0.000701139,0.0005136555],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002460085,"about_ca_system_score_gemma":0.0001479763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000167077,"about_ca_topic_score_gemma":0.0004909282,"domain_scores_codex":[0.9998605,0.00002070389,0.000007418998,0.00002585359,0.00005367308,0.00003181414],"domain_scores_gemma":[0.9999117,0.00002294061,0.00001435895,0.00002372662,0.00001246563,0.0000148093],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003192107,0.00002328517,0.00008310341,0.00006508812,0.000005898523,0.00006616956,0.00002739475,0.0002430342,0.9907979,0.001284425,0.000191552,0.007180283],"study_design_scores_gemma":[0.000009825125,0.000159622,0.0002527287,0.000007147379,0.000006009817,0.0001509829,0.00002234132,0.001423356,0.9916953,0.0002731651,0.00599412,0.000005349893],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.954459,0.007836827,0.02762232,0.001130976,0.00009717442,0.00008963301,0.0001888728,0.000418918,0.008156401],"genre_scores_gemma":[0.9877099,0.002757169,0.007076772,0.00007098023,0.00002320301,0.00002051586,0.0001305295,0.00004321112,0.002167632],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009067005,"threshold_uncertainty_score":0.003033221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03142262051092045,"score_gpt":0.2763367018998316,"score_spread":0.2449140813889111,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}