{"id":"W4320920568","doi":"10.4236/ojic.2023.131001","title":"Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C&amp;lt;sub&amp;gt;6&amp;lt;/sub&amp;gt;H&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt;(NH&amp;lt;sub&amp;gt;3&amp;lt;/sub&amp;gt;)&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;Cl&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt; (I), &amp;lt;i&amp;gt;β&amp;lt;/i&amp;gt;-[C&amp;lt;sub&amp;gt;6&amp;lt;/sub&amp;gt;H&amp;lt;sub&amp;gt;10&amp;lt;/sub&amp;gt;N&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;]&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;ZnCl&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; (II), Respectively","year":2023,"lang":"en","type":"article","venue":"Open Journal of Inorganic Chemistry","topic":"Solid-state spectroscopy and crystallography","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Centre National de la Recherche Scientifique","keywords":"Monoclinic crystal system; Infrared spectroscopy; Cationic polymerization; Crystallography; Crystal structure; Spectroscopy; Single crystal; Intermolecular force; Hydrogen bond; Chemistry; Chloride; Absorption spectroscopy; Nuclear magnetic resonance spectroscopy; Hydrothermal circulation; Inorganic chemistry; Stereochemistry; Molecule; Organic chemistry; Chemical engineering","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.07179426,0.07722142,0.07433719,0.04265897,0.04200999,0.03669934,0.07229171,0.04679974,0.04993313],"category_scores_gemma":[0.05827785,0.0827461,0.04118698,0.07317673,0.04080345,0.03256276,0.04623032,0.06838818,0.07123961],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.03902097,"about_ca_system_score_gemma":0.02793107,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004569009,"about_ca_topic_score_gemma":0.1547145,"domain_scores_codex":[0.7282356,0.03703168,0.06380247,0.05669322,0.05299104,0.061246],"domain_scores_gemma":[0.7623264,0.03552956,0.06174323,0.06872114,0.0326868,0.03899286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0343834,0.01985611,0.004328551,0.013499,0.02373606,0.0010842,0.02118282,0.009074852,0.6068081,0.00154056,0.2586796,0.005826754],"study_design_scores_gemma":[0.05516606,0.004799755,0.003503039,0.02691386,0.03186754,0.02354771,0.002075592,0.000223904,0.08996157,0.008407588,0.6865673,0.06696605],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7112389,0.0698209,0.04534581,0.007429762,0.03826303,0.04290054,0.05553912,0.02007437,0.009387564],"genre_scores_gemma":[0.5701116,0.06929321,0.08503283,0.009034378,0.03395093,0.01164568,0.1284436,0.02907187,0.06341598],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5168465,"threshold_uncertainty_score":0.9809683,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0169045461979119,"score_gpt":0.2701437455360683,"score_spread":0.2532391993381564,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}