{"id":"W4321033385","doi":"10.1021/acs.macromol.2c02248","title":"Toward Defect Suppression in Polythiophenes Synthesized by Direct (Hetero)Arylation Polymerization","year":2023,"lang":"en","type":"article","venue":"Macromolecules","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymer; Monomer; Polymer chemistry; Polymerization; Size-exclusion chromatography; Chemistry; Differential scanning calorimetry; Diamine; Branching (polymer chemistry); Solvent; Moiety; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001677701,0.0004864925,0.0001869734,0.0001124138,0.0001053479,0.0002334332,0.000166489,0.0002421151,0.0007212448],"category_scores_gemma":[0.000229524,0.0001357117,0.000168785,0.0001670771,0.0001718441,0.0002457422,0.0001832818,0.0005400605,0.0002903717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001127065,"about_ca_system_score_gemma":0.0001186714,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002669593,"about_ca_topic_score_gemma":0.0006387816,"domain_scores_codex":[0.999838,0.000025664,0.00001117708,0.00004073786,0.0000482984,0.00003615948],"domain_scores_gemma":[0.999819,0.00006020207,0.00005365207,0.00002089609,0.0000280268,0.0000183007],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001186433,0.000007336592,0.00004230659,0.00003065172,0.00000191254,0.00002391549,0.00001248113,0.00005141315,0.9991379,0.00002564251,0.00000481587,0.0006497063],"study_design_scores_gemma":[0.000001620356,0.00005160486,0.0001626648,0.000001361774,0.000003135805,0.00002581411,0.000003365431,0.0002133886,0.9992937,0.000006331728,0.0002357134,0.000001325727],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903339,0.001177477,0.007341254,0.00003508171,0.00001320547,0.00002551166,0.00006089294,0.00006643955,0.0009462315],"genre_scores_gemma":[0.9909124,0.001015842,0.006515571,0.00001983095,0.000007268842,0.0000239595,0.00009592497,0.00003760412,0.001371481],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007212448,"threshold_uncertainty_score":0.002412796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0201496757108652,"score_gpt":0.2602162860366345,"score_spread":0.2400666103257693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}