{"id":"W4321328136","doi":"10.1002/chem.202204018","title":"Unexpectedly Large Structural Variations in Benzyl‐Substituted Sila[1]ferrocenophanes","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dihedral angle; Steric effects; Crystallography; Chemistry; Conformational isomerism; Crystal structure; Molecular geometry; Molecule; Atom (system on chip); Planar; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008452918,0.0002595655,0.0001636673,0.0001455848,0.0001409055,0.0001296051,0.0001352104,0.0001750594,0.0017046],"category_scores_gemma":[0.0002034076,0.0001241542,0.00008004815,0.0001496685,0.0002283224,0.0001904912,0.0001340033,0.0002344841,0.0001318437],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001393704,"about_ca_system_score_gemma":0.0001195021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000299479,"about_ca_topic_score_gemma":0.0006282069,"domain_scores_codex":[0.9999354,0.00001067192,0.000004911392,0.00001509302,0.00001512672,0.00001878228],"domain_scores_gemma":[0.9999195,0.00002200121,0.00002458736,0.00001035044,0.00001193626,0.00001160944],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001396404,0.00001490615,0.0003422429,0.0000518268,0.000007968677,0.0001662226,0.00004619398,0.0002904508,0.9965976,0.0002432805,0.00005399928,0.002045779],"study_design_scores_gemma":[0.00004253541,0.0006425189,0.004423498,0.00001080736,0.00002010679,0.0003480976,0.00006297991,0.000809166,0.9912499,0.0001234293,0.002256907,0.00000999543],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982268,0.000162386,0.0003016474,0.00002286096,0.000004357053,0.000005749961,0.0001024235,0.00001168912,0.001161999],"genre_scores_gemma":[0.9984957,0.0002350894,0.0004586408,0.00001484307,0.000002285446,0.00001012539,0.0001580055,0.000008219132,0.0006170228],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0017046,"threshold_uncertainty_score":0.005702496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01546837249054213,"score_gpt":0.2293330866605809,"score_spread":0.2138647141700388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}