{"id":"W4321436207","doi":"10.1021/acsapm.3c00168","title":"Photoiniferter RAFT Polymerization of Optically Active Hydrophilic Vitamin B5 Analogous Methacrylamide","year":2023,"lang":"en","type":"article","venue":"ACS Applied Polymer Materials","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Prince Edward Island","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Methacrylamide; Polymerization; Reversible addition−fragmentation chain-transfer polymerization; Specific rotation; Enantiomer; Polymer chemistry; Monomer; Polymer; Circular dichroism; Optical rotation; Chain transfer; Chemistry; Materials science; Radical polymerization; Organic chemistry; Stereochemistry; Acrylamide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009185207,0.0002468318,0.00007358102,0.000126103,0.00008664552,0.0001247824,0.00008505782,0.0001713312,0.0009211948],"category_scores_gemma":[0.0001121926,0.00008629623,0.0001320105,0.00007097621,0.00009823204,0.0002333594,0.0001022026,0.0002842493,0.0001915323],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001046656,"about_ca_system_score_gemma":0.00008991353,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001755362,"about_ca_topic_score_gemma":0.0005525377,"domain_scores_codex":[0.9999517,0.000008014705,0.00000329302,0.00001312832,0.00001244858,0.00001142972],"domain_scores_gemma":[0.9999359,0.00001637033,0.00002676455,0.000005142279,0.000005674072,0.00001007577],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001815379,0.000008077545,0.00003587003,0.00002415098,0.00000166651,0.00002483498,0.00001381489,0.00003595871,0.9983647,0.00009553546,0.000008704606,0.001368351],"study_design_scores_gemma":[0.0000023057,0.00007193347,0.0004284864,0.000002610372,0.000003180462,0.00006379215,0.000007556035,0.000230855,0.9981567,0.00001508492,0.001015194,0.000002370828],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913805,0.001132933,0.004620206,0.00004961203,0.0000147128,0.00002577021,0.00005864096,0.00004832399,0.00266939],"genre_scores_gemma":[0.9940626,0.0006474335,0.003655593,0.00002255431,0.00000647452,0.00001308787,0.0000439345,0.0000112983,0.001536966],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009211948,"threshold_uncertainty_score":0.003081679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009495451675936182,"score_gpt":0.2336742007775683,"score_spread":0.2241787491016321,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}