{"id":"W4321606668","doi":"10.1021/acs.langmuir.2c02864","title":"Monomeric and Polymeric Mesoionic <i>N</i>-Heterocyclic Carbene-Tethered Silver Nanoparticles: Synthesis, Stability, and Catalytic Activity","year":2023,"lang":"en","type":"article","venue":"Langmuir","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Division of Electrical, Communications and Cyber Systems; Natural Sciences and Engineering Research Council of Canada; University of Central Florida","keywords":"Chemistry; Mesoionic; Monomer; Click chemistry; Combinatorial chemistry; Nanoparticle; Polymerization; Polymer; Triazole; Catalysis; Polymer chemistry; Silver nanoparticle; Organic chemistry; Materials science; Nanotechnology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001481231,0.0002510498,0.0001268512,0.0001533365,0.00009188132,0.0002735993,0.00033237,0.0003095135,0.0003643277],"category_scores_gemma":[0.0001920168,0.0001562655,0.0001598564,0.0001325751,0.0002022416,0.0001710604,0.0001359548,0.0003588529,0.0002274388],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003781695,"about_ca_system_score_gemma":0.0001474879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007548368,"about_ca_topic_score_gemma":0.001336635,"domain_scores_codex":[0.9998721,0.00001035899,0.00001090089,0.00003768908,0.00004891153,0.0000201135],"domain_scores_gemma":[0.9998944,0.00001610781,0.00003532481,0.00001286681,0.00001908022,0.00002224017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002694321,0.00001095052,0.00005921757,0.00003022318,0.000002846458,0.00003372633,0.00001255884,0.0001010636,0.9975302,0.000118857,0.00002391854,0.002049464],"study_design_scores_gemma":[0.000002832755,0.000064782,0.0003841733,0.000001546852,0.000004870196,0.00006472308,0.00000410107,0.0005134489,0.9982419,0.00001533862,0.0006986155,0.000003538632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9801955,0.005314911,0.008217773,0.0001471787,0.00003509954,0.00004482451,0.0001144936,0.0001507453,0.005779585],"genre_scores_gemma":[0.9925321,0.00101966,0.003840654,0.00003847027,0.00001059262,0.00001416113,0.00008541314,0.0000195274,0.002439394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007548368,"threshold_uncertainty_score":0.0027439,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01538362577356083,"score_gpt":0.2284626548130806,"score_spread":0.2130790290395198,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}