{"id":"W4322488432","doi":"10.1021/acsomega.2c06394","title":"One-Pot Synthesis of Cyclomatrix-Type Polyphosphazene Microspheres and Their High Thermal Stability","year":2023,"lang":"en","type":"article","venue":"ACS Omega","topic":"Flame retardant materials and properties","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; Centre québécois sur les matériaux fonctionnels; Université du Québec à Montréal","keywords":"Thermogravimetric analysis; Thermal stability; Polyphosphazene; Fourier transform infrared spectroscopy; Epoxy; Scanning electron microscope; X-ray photoelectron spectroscopy; Raman spectroscopy; Materials science; Diglycidyl ether; Polymerization; Triethylamine; Nuclear chemistry; Polymer chemistry; Thermosetting polymer; Chemistry; Analytical Chemistry (journal); Chemical engineering; Polymer; Bisphenol A; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001508435,0.0003691607,0.0001790643,0.0001534258,0.0001150205,0.0001503046,0.0001367423,0.0002525334,0.000706945],"category_scores_gemma":[0.0001224706,0.0001931548,0.0001814331,0.000141963,0.000138773,0.0002220276,0.00017514,0.0003544322,0.0003005284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002215718,"about_ca_system_score_gemma":0.0001860343,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00056703,"about_ca_topic_score_gemma":0.001085183,"domain_scores_codex":[0.9999058,0.000006872438,0.000006594168,0.00003151333,0.00003261119,0.00001662086],"domain_scores_gemma":[0.9999157,0.00001331561,0.0000296509,0.000007310917,0.00001879212,0.00001514743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009078301,0.00000249422,0.00002262326,0.00001625446,0.00000144145,0.0000143644,0.000004815554,0.00003723399,0.9989368,0.0000373201,0.00001033705,0.000907285],"study_design_scores_gemma":[0.000004513116,0.00007331224,0.0008654468,0.000001178217,0.000004551077,0.00007495422,0.000003759144,0.0002970485,0.99768,0.00001475137,0.0009763383,0.000004191209],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9398462,0.002273164,0.05368171,0.0001056018,0.0000394694,0.0001958542,0.0006688524,0.0003455883,0.002843512],"genre_scores_gemma":[0.9638861,0.001146458,0.03141779,0.00002957051,0.00001456991,0.000190821,0.0003950993,0.00005705185,0.002862521],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000706945,"threshold_uncertainty_score":0.002364933,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02197624675410651,"score_gpt":0.2174519069120772,"score_spread":0.1954756601579707,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}