{"id":"W4322488432","doi":"10.1021/acsomega.2c06394","title":"One-Pot Synthesis of Cyclomatrix-Type Polyphosphazene Microspheres and Their High Thermal Stability","year":2023,"lang":"en","type":"article","venue":"ACS Omega","topic":"Flame retardant materials and properties","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; Centre québécois sur les matériaux fonctionnels; Université du Québec à Montréal","keywords":"Thermogravimetric analysis; Thermal stability; Polyphosphazene; Fourier transform infrared spectroscopy; Epoxy; Scanning electron microscope; X-ray photoelectron spectroscopy; Raman spectroscopy; Materials science; Diglycidyl ether; Polymerization; Triethylamine; Nuclear chemistry; Polymer chemistry; Thermosetting polymer; Chemistry; Analytical Chemistry (journal); Chemical engineering; Polymer; Bisphenol A; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005997564,0.0001718996,0.000395059,0.00003479507,0.0001147266,0.00008815783,0.0002628591,0.00008638869,0.0003309137],"category_scores_gemma":[0.0001797772,0.0001238103,0.00004269262,0.0002070724,0.0002406484,0.0001725175,0.0002119197,0.00004751137,0.0001656409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001529294,"about_ca_system_score_gemma":0.00004710918,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007980107,"about_ca_topic_score_gemma":0.0000265187,"domain_scores_codex":[0.9987504,0.0001296007,0.0003271476,0.0002996275,0.0001679966,0.0003252546],"domain_scores_gemma":[0.999109,0.0002535097,0.0001142984,0.00038053,0.00007893857,0.000063687],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001664642,0.00003142204,0.00146204,0.0001617107,0.00001827486,0.000001755631,0.0004155157,0.000009095587,0.9946402,0.0001509581,0.0001135448,0.002828963],"study_design_scores_gemma":[0.0001340705,0.00008075511,0.02865358,0.00005172974,0.00001601236,0.000001740453,0.0001589597,0.00001314758,0.9699106,0.0004571821,0.0003660773,0.0001561963],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976625,0.0009937505,0.000001582666,0.0002556054,0.0004145237,0.0001639186,0.0001233451,0.0001507737,0.0002340119],"genre_scores_gemma":[0.9991074,0.0003655452,0.0002640965,0.00003167308,0.00006732556,0.00001426781,0.000005258673,0.00002572752,0.0001187109],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02719154,"threshold_uncertainty_score":0.5048837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02197624675410651,"score_gpt":0.2174519069120772,"score_spread":0.1954756601579707,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}