{"id":"W4322733151","doi":"10.1021/acs.organomet.2c00609","title":"Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand","year":2023,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of Calgary","funders":"Chinese Academy of Sciences; Natural Sciences and Engineering Research Council of Canada; Institut Universitaire de France; Canada Research Chairs; Alexander von Humboldt-Stiftung","keywords":"Chemistry; Hydride; Dimer; Dissociation (chemistry); Ligand (biochemistry); Alkyl; Homolysis; Singlet state; Cyclohexene oxide; Medicinal chemistry; Photochemistry; Crystallography; Metal; Cyclohexene; Physical chemistry; Radical; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006423734,0.000248384,0.0002039459,0.0001216904,0.0001453231,0.0003679,0.0005333745,0.00023034,0.001688911],"category_scores_gemma":[0.0001009378,0.0001737196,0.00009330738,0.0001323138,0.0001879726,0.0001746792,0.0004401407,0.0003880444,0.0004337624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004331983,"about_ca_system_score_gemma":0.0001696772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009459984,"about_ca_topic_score_gemma":0.001234797,"domain_scores_codex":[0.9999341,0.000007383601,0.000005103469,0.00001246682,0.00002189987,0.00001897533],"domain_scores_gemma":[0.9999601,0.000006164644,0.00001101297,0.000004393592,0.000005069771,0.00001323685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002043619,0.00002379254,0.0001551692,0.0001022508,0.000008843126,0.00006604522,0.0000425955,0.0008570594,0.9950806,0.001319768,0.0001339334,0.002005486],"study_design_scores_gemma":[0.00006139978,0.0003414508,0.0006740463,0.00001263833,0.00001862375,0.00007800155,0.00004004664,0.004913899,0.9883832,0.0001674884,0.005293767,0.00001540717],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992245,0.0003749052,0.00274265,0.00006070541,0.00002303528,0.00001249572,0.00009935591,0.0001255598,0.004316211],"genre_scores_gemma":[0.9957992,0.0002233725,0.002058081,0.00001907798,0.000003383349,0.00001246182,0.0001484553,0.00002045824,0.001715347],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001688911,"threshold_uncertainty_score":0.005649924,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01517221130062161,"score_gpt":0.2342433805191918,"score_spread":0.2190711692185702,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}