{"id":"W4323065392","doi":"10.1039/d3dt00224a","title":"Spectroscopy, molecular structure, and electropolymerization of Ni(<scp>ii</scp>) and Cu(<scp>ii</scp>) complexes containing a thiophene-appending fluorinated Schiff base ligand","year":2023,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Centre National de la Recherche Scientifique; Comisión Nacional de Investigación Científica y Tecnológica; Fondo Nacional de Desarrollo Científico y Tecnológico; Université de Rennes 1; Pontificia Universidad Católica de Valparaíso; Kungliga Tekniska Högskolan","keywords":"Thiophene; Chemistry; Schiff base; Trifluoromethyl; Ligand (biochemistry); Crystallography; Electrochemistry; Stereochemistry; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007862729,0.0001634211,0.00004875883,0.0001513447,0.00008437069,0.00008898898,0.0001241258,0.0001886891,0.001532846],"category_scores_gemma":[0.0001954465,0.00009896796,0.0000779706,0.0001439097,0.000127739,0.0001015645,0.00005088609,0.0002855645,0.0001781354],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001479084,"about_ca_system_score_gemma":0.0001105346,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001008275,"about_ca_topic_score_gemma":0.00110069,"domain_scores_codex":[0.9999557,0.000004108772,0.000001862674,0.00001238067,0.00001519334,0.00001078414],"domain_scores_gemma":[0.9999263,0.00001860913,0.00002543173,0.000005295797,0.00001201667,0.00001227907],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002747714,0.000006564476,0.0001200439,0.00001570991,0.000002503322,0.00002067627,0.00001745393,0.00004949235,0.9981993,0.0000877275,0.00005707073,0.001395933],"study_design_scores_gemma":[0.000002335601,0.00005707757,0.0034955,0.000002946603,0.000005234544,0.0001032822,0.0000113072,0.0005963204,0.9950493,0.00002580074,0.0006487799,0.000002068643],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903888,0.0009463878,0.004951143,0.0001537548,0.00002153199,0.00001417759,0.0002889848,0.00006651419,0.003168671],"genre_scores_gemma":[0.9958214,0.0004396271,0.001509065,0.00002968543,0.000006193466,0.00001111175,0.0002132269,0.000009303018,0.00196057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001532846,"threshold_uncertainty_score":0.005127907,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02087338633385125,"score_gpt":0.2583694591552325,"score_spread":0.2374960728213812,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}