{"id":"W4323065392","doi":"10.1039/d3dt00224a","title":"Spectroscopy, molecular structure, and electropolymerization of Ni(<scp>ii</scp>) and Cu(<scp>ii</scp>) complexes containing a thiophene-appending fluorinated Schiff base ligand","year":2023,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Centre National de la Recherche Scientifique; Comisión Nacional de Investigación Científica y Tecnológica; Fondo Nacional de Desarrollo Científico y Tecnológico; Université de Rennes 1; Pontificia Universidad Católica de Valparaíso; Kungliga Tekniska Högskolan","keywords":"Thiophene; Chemistry; Schiff base; Trifluoromethyl; Ligand (biochemistry); Crystallography; Electrochemistry; Stereochemistry; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002508888,0.0003657472,0.0006781401,0.0004674046,0.000807239,0.00007165702,0.000114212,0.000153679,0.00002592031],"category_scores_gemma":[0.0002015879,0.000331088,0.0001195832,0.0007525246,0.0002493966,0.0002211985,0.00003762609,0.0003826653,0.000004294117],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004036825,"about_ca_system_score_gemma":0.00009212048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002571151,"about_ca_topic_score_gemma":0.00005238642,"domain_scores_codex":[0.9979095,0.0001326109,0.0005209401,0.0005238335,0.0003826517,0.0005304347],"domain_scores_gemma":[0.9988592,0.0002908887,0.0001850225,0.0003212054,0.0001088624,0.0002348479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005335158,0.00007194043,0.0008222414,0.0002676317,0.0002197928,0.00001319494,0.001569067,0.0000447825,0.9948269,0.001263574,0.00006412844,0.000783398],"study_design_scores_gemma":[0.001159331,0.001039036,0.004559312,0.0002049559,0.0003524855,0.0000930458,0.00156324,0.001724241,0.9875956,0.0006286117,0.0009810401,0.00009905752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899846,0.002190555,0.005862212,0.0002080777,0.0001644126,0.0005295408,0.0001388468,0.0002176249,0.0007040786],"genre_scores_gemma":[0.9968325,0.0008363097,0.001282508,0.0001162805,0.00006102003,0.00002885275,0.0001602428,0.00007206765,0.0006102266],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007231253,"threshold_uncertainty_score":0.9999141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02087338633385125,"score_gpt":0.2583694591552325,"score_spread":0.2374960728213812,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}