{"id":"W4323313918","doi":"10.1002/zaac.202300007","title":"Facile Synthesis of (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BBr and (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BX(OEt<sub>2</sub>) (X=Cl, Br) using Hydrogen Halides and Piers’ Borane","year":2023,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"National Science Foundation","keywords":"Protonolysis; Yield (engineering); Chemistry; Borane; Medicinal chemistry; Physics; Stereochemistry; Crystallography; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001335635,0.000330699,0.0001684291,0.000184324,0.0001330913,0.0002185071,0.0002220957,0.0002191784,0.002528206],"category_scores_gemma":[0.0001007986,0.0001595468,0.0001653282,0.0001290186,0.0001740061,0.0002970375,0.0003534512,0.0003326601,0.0009427973],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002052823,"about_ca_system_score_gemma":0.0002039376,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004065814,"about_ca_topic_score_gemma":0.001197594,"domain_scores_codex":[0.9999199,0.000008665339,0.000005392462,0.00001670881,0.00002533561,0.00002403078],"domain_scores_gemma":[0.9999682,0.000003841572,0.000008478475,0.000005790741,0.000005892246,0.000007875181],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000689022,0.00001495041,0.00008667198,0.000142861,0.000009415294,0.00009763183,0.00006932079,0.0002247712,0.9910371,0.001133582,0.0001768712,0.006937853],"study_design_scores_gemma":[0.00001198389,0.0001346438,0.0003272848,0.000003961695,0.000008127862,0.0001209809,0.00002677271,0.0002951084,0.9932142,0.00008931015,0.005760256,0.000007373915],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9539456,0.00239997,0.02442828,0.0001636538,0.00007484177,0.0001009091,0.0005679786,0.0004128237,0.01790588],"genre_scores_gemma":[0.9795409,0.001190557,0.01255283,0.00005767518,0.000009299624,0.00003696164,0.0004041898,0.00006510838,0.006142382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002528206,"threshold_uncertainty_score":0.00845772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01328725598123264,"score_gpt":0.2382563749186478,"score_spread":0.2249691189374152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}