{"id":"W4323313918","doi":"10.1002/zaac.202300007","title":"Facile Synthesis of (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BBr and (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BX(OEt<sub>2</sub>) (X=Cl, Br) using Hydrogen Halides and Piers’ Borane","year":2023,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"National Science Foundation","keywords":"Protonolysis; Yield (engineering); Chemistry; Borane; Medicinal chemistry; Physics; Stereochemistry; Crystallography; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.003323243,0.008100858,0.007862518,0.002163177,0.003193617,0.002067225,0.004818109,0.006281348,0.0003060595],"category_scores_gemma":[0.004030003,0.009274004,0.002847831,0.006227287,0.004209092,0.00335289,0.004901242,0.006319931,0.001767524],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001063058,"about_ca_system_score_gemma":0.002818656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001711305,"about_ca_topic_score_gemma":0.000558815,"domain_scores_codex":[0.96837,0.0008757127,0.007478851,0.009286141,0.005531478,0.008457842],"domain_scores_gemma":[0.9784704,0.00285922,0.004456537,0.006912434,0.002155157,0.005146209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001054363,0.002080245,0.004861671,0.006230912,0.004120621,0.001269501,0.001909562,0.0002330695,0.9560825,0.000115012,0.01075593,0.01128662],"study_design_scores_gemma":[0.008794258,0.0004915156,0.00175391,0.002682624,0.004502517,0.00110681,0.002061222,0.0008301348,0.9648272,0.0002222261,0.003294281,0.009433258],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777747,0.007051107,0.0002049084,0.001596444,0.001358549,0.002897154,0.00365004,0.003699609,0.001767491],"genre_scores_gemma":[0.9710372,0.01708957,0.0003216247,0.001252264,0.003504232,0.0006312279,0.003067738,0.002994287,0.0001018556],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01010047,"threshold_uncertainty_score":0.9990097,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01328725598123264,"score_gpt":0.2382563749186478,"score_spread":0.2249691189374152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}