{"id":"W4327684948","doi":"10.1039/d2cc06077a","title":"Coinage metal amido and thiolate SNS complexes: consequences of catalyst speciation in Cu(<scp>i</scp>)-catalysed carbonyl hydroboration","year":2023,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University; University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydroboration; Chemistry; Catalysis; Ligand (biochemistry); Medicinal chemistry; Metal; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002370865,0.000227075,0.0003544575,0.000179058,0.0001955467,0.0004541921,0.0004581148,0.0003687417,0.001066715],"category_scores_gemma":[0.0003383813,0.0002083014,0.0001324008,0.0001637969,0.0003032786,0.0002197551,0.0002855841,0.0002237854,0.0002662227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004738331,"about_ca_system_score_gemma":0.0001360972,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001713074,"about_ca_topic_score_gemma":0.004558744,"domain_scores_codex":[0.9997794,0.0000474258,0.00002072663,0.00004695632,0.00006089431,0.00004452672],"domain_scores_gemma":[0.9998512,0.00003056492,0.00003193863,0.00001829341,0.00003817017,0.00002985572],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004770079,0.00001859267,0.0002552858,0.00005774032,0.00001894428,0.00003838683,0.00005002028,0.0001304881,0.9974998,0.0001720475,0.00005033525,0.001231416],"study_design_scores_gemma":[0.00001341417,0.0001869135,0.0004254025,0.000002493482,0.00001392365,0.0000384668,0.0000264361,0.0003147268,0.9984031,0.000009575472,0.000561674,0.000003785795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977005,0.000366647,0.0005461873,0.0000212208,0.00001010283,0.00001586127,0.00005810645,0.00002950797,0.001251743],"genre_scores_gemma":[0.9981672,0.0001745868,0.0006093337,0.000009069239,0.000002609252,0.000008470933,0.00008690174,0.00001523756,0.0009265701],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001713074,"threshold_uncertainty_score":0.00356853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03286961174979092,"score_gpt":0.2764662300507001,"score_spread":0.2435966183009092,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}