{"id":"W4360828064","doi":"10.1021/jacs.3c00882","title":"A Robust, Divalent, Phosphaza-bicyclo[2.2.2]octane Connector Provides Access to Cage-Dense Inorganic Polymers and Networks","year":2023,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Chemistry; Octane; Divalent; Cage; Bicyclic molecule; Polymer; DABCO; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001913143,0.0002501681,0.0004493165,0.00001596597,0.0001544937,0.0001327876,0.0009193734,0.00009434454,0.0001804394],"category_scores_gemma":[0.0002903175,0.0001845084,0.0004730413,0.0007222483,0.0003878164,0.0001104346,0.0006236563,0.0005974678,0.000003371602],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001390574,"about_ca_system_score_gemma":0.00008138954,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005767668,"about_ca_topic_score_gemma":0.000001013594,"domain_scores_codex":[0.998405,0.0000303852,0.0004213765,0.0002837725,0.0004113727,0.000448121],"domain_scores_gemma":[0.9984535,0.0002773769,0.0005334176,0.0003517233,0.0000817256,0.0003022611],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001191812,0.00005284086,0.00717807,0.00006373435,0.0002503752,0.0000201572,0.000287155,0.000223463,0.9717333,0.000002139391,0.01786952,0.00220011],"study_design_scores_gemma":[0.0007042919,0.0000458868,0.002066843,0.0001575824,0.0001831316,0.0002451036,0.001536505,0.00152053,0.9899203,0.0000993939,0.003109563,0.0004108661],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960995,0.0003639133,0.0001273931,0.003010866,0.00009492246,0.00006249813,0.00001358295,0.00006220174,0.0001651325],"genre_scores_gemma":[0.9968746,0.0002213556,0.0003417011,0.001683971,0.000497685,0.000007236973,0.0000036577,0.00004192798,0.0003278721],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01818705,"threshold_uncertainty_score":0.7524034,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01955591917833431,"score_gpt":0.2545312115636984,"score_spread":0.2349752923853641,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}