{"id":"W4360863538","doi":"10.3390/molecules28072900","title":"Phthalylglycyl Chloride as a Derivatization Agent for UHPLC-MS/MS Determination of Adrenaline, Dopamine and Octopamine in Urine","year":2023,"lang":"en","type":"article","venue":"Molecules","topic":"Pharmacological Effects and Assays","field":"Agricultural and Biological Sciences","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"CanAm Bioresearch (Canada)","funders":"","keywords":"Derivatization; Octopamine (neurotransmitter); Chemistry; Chromatography; Urine; Dopamine; Mass spectrometry; Biochemistry; Internal medicine; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001995472,0.00009978325,0.0001556873,0.00003038949,0.00005013026,0.00001812012,0.00008679386,0.00004949905,0.00005639841],"category_scores_gemma":[0.0001921266,0.00004210936,0.00004072097,0.0003792112,0.0000346934,0.0000551639,0.00005600596,0.0000388869,0.000004014881],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000105771,"about_ca_system_score_gemma":0.000003222394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001149498,"about_ca_topic_score_gemma":0.0001041307,"domain_scores_codex":[0.9992857,0.00003554735,0.000198056,0.0001974528,0.0001130217,0.000170211],"domain_scores_gemma":[0.9995686,0.0002414566,0.00007891667,0.00002580924,0.00004340523,0.0000418241],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00008176303,0.00008809462,0.002644624,0.00004076637,0.000004333636,0.000021028,0.00001966292,0.00003412079,0.9317402,0.0002716942,0.00006250485,0.06499125],"study_design_scores_gemma":[0.0009079807,0.0009750599,0.4956695,0.00007111031,0.00002018548,0.000008474844,0.00005184672,0.01508716,0.4814321,0.002064297,0.003469532,0.0002427547],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984136,0.00006814487,0.0001683634,0.0007007736,0.00004286473,0.0003299484,0.00003270698,0.00003857176,0.0002050039],"genre_scores_gemma":[0.9991801,0.00009653037,0.0001412284,0.0001240597,0.00007711112,0.00006837728,0.0001739692,0.00000123485,0.0001374336],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4930249,"threshold_uncertainty_score":0.171717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02227325130268202,"score_gpt":0.2745832754467942,"score_spread":0.2523100241441122,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}