{"id":"W4362557266","doi":"10.1002/ange.202302994","title":"Heterogeneous Photocatalytic Recycling of FeX<sub>2</sub>/FeX<sub>3</sub> for Efficient Halogenation of C−H Bonds Using NaX","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"Engineering and Physical Sciences Research Council; Canada Excellence Research Chairs, Government of Canada; Suzhou Municipal Science and Technology Bureau; National Natural Science Foundation of China","keywords":"Halogenation; Halogen; Photocatalysis; Chemistry; Selectivity; Photochemistry; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009991288,0.0002979417,0.0001840803,0.0001109702,0.0001146611,0.0002875285,0.0002637257,0.0002724347,0.0005376657],"category_scores_gemma":[0.00008875727,0.0001285186,0.0001343704,0.00009151643,0.0001346615,0.000228827,0.0001996952,0.0002465544,0.0002058445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003083304,"about_ca_system_score_gemma":0.0001385275,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007955749,"about_ca_topic_score_gemma":0.001642759,"domain_scores_codex":[0.999925,0.000007476327,0.000004802945,0.0000233624,0.00002222219,0.00001725161],"domain_scores_gemma":[0.9999721,0.000003535467,0.000008150561,0.000004312323,0.000007849299,0.000004105984],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002244128,0.000009514975,0.00008073834,0.00003064511,0.000005417521,0.00002748527,0.00001231884,0.0001174389,0.9980406,0.000111398,0.00005260522,0.001489397],"study_design_scores_gemma":[0.000003867533,0.00003732993,0.0002060367,0.000001933954,0.00000338827,0.00002337469,0.000006162944,0.001015143,0.9980915,0.0000149375,0.0005941205,0.000002095243],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920605,0.000669341,0.005458063,0.00006102244,0.00002661656,0.00001949939,0.00005719646,0.0001644242,0.001483194],"genre_scores_gemma":[0.9961144,0.0001868653,0.002089321,0.00001761796,0.000002556936,0.000006697113,0.00003726604,0.0000147735,0.001530445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007955749,"threshold_uncertainty_score":0.002237141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03104451451758257,"score_gpt":0.2647567329760175,"score_spread":0.2337122184584349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}