{"id":"W4362563115","doi":"10.2139/ssrn.4409400","title":"Toward a Mechanistic Understanding of Rhenium(Vii) Adsorption Behavior Onto Primary, Secondary, Tertiary and Quaternary Amino Groups in Polymeric Adsorbents: Batch Experiments, Spectroscopic Analyses, and Theoretical Computations","year":2023,"lang":"en","type":"preprint","venue":"SSRN Electronic Journal","topic":"Extraction and Separation Processes","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"","keywords":"Adsorption; Rhenium; Primary (astronomy); Quaternary; Computation; Chemistry; Chemical engineering; Materials science; Inorganic chemistry; Organic chemistry; Geology; Physics; Mathematics; Engineering; Paleontology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000468534,0.0003422965,0.0004881091,0.0005295445,0.00009038766,0.0001384581,0.0001748886,0.0002206326,0.00006247008],"category_scores_gemma":[0.00001805896,0.0003575679,0.00009369278,0.0001977316,0.000113342,0.0002412411,0.0001150217,0.00194509,0.000003280075],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001459289,"about_ca_system_score_gemma":0.0005738764,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001334753,"about_ca_topic_score_gemma":0.0002927575,"domain_scores_codex":[0.9976255,0.0001151408,0.0007302779,0.0003640403,0.0003153949,0.0008496189],"domain_scores_gemma":[0.9993848,0.00008019145,0.0002230745,0.0001531438,0.00004224357,0.0001165824],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0004873658,0.001050696,0.02502107,0.003444312,0.002615288,0.000149689,0.01134581,0.009388543,0.3065949,0.6324185,0.000174968,0.007308849],"study_design_scores_gemma":[0.004226958,0.0009249816,0.03189826,0.001179172,0.001004274,0.001236396,0.02028072,0.09470495,0.01306588,0.8296332,0.0000144494,0.001830724],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7186032,0.01000936,0.269908,0.0001463386,0.00051824,0.0003960601,0.00002433759,0.000144021,0.0002504431],"genre_scores_gemma":[0.9868851,0.01237736,0.0003373065,0.00002256791,0.00008128782,0.00004815835,0.00009974364,0.00006305248,0.00008547156],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2935291,"threshold_uncertainty_score":0.9998876,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04467291672202459,"score_gpt":0.3134552625304313,"score_spread":0.2687823458084067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}