{"id":"W4362591971","doi":"10.51167/acm00038","title":"Gold Catalysis: A New Contender for Cross-Coupling Reactions with Aryl Halides","year":2023,"lang":"en","type":"article","venue":"","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Aryl; Halide; Catalysis; Coupling reaction; Chemistry; Oxidative addition; Heteroatom; Coupling (piping); Carbon fibers; Combinatorial chemistry; Polymer chemistry; Organic chemistry; Materials science; Ring (chemistry); Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001740301,0.0002695658,0.0002948593,0.0001166987,0.0003309124,0.0003418402,0.0002434166,0.000158529,0.0004657375],"category_scores_gemma":[0.0001824772,0.0002387152,0.0002230388,0.0005757391,0.0001504032,0.0003145909,0.00006763411,0.0002392996,0.0003303684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001583784,"about_ca_system_score_gemma":0.0002332625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002284935,"about_ca_topic_score_gemma":0.0004654473,"domain_scores_codex":[0.9982013,1.105518e-7,0.0004143307,0.0005838068,0.0002702171,0.000530283],"domain_scores_gemma":[0.9982603,0.0003944826,0.0001484498,0.0007509362,0.000230086,0.0002157818],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002531346,0.0001976917,0.00741128,0.0004753437,0.0009311232,0.00004420707,0.0004550064,0.01345955,0.9535756,0.002429487,0.01995238,0.0008152107],"study_design_scores_gemma":[0.003724315,0.00005190199,0.001885799,0.000464604,0.0005195261,0.0002007644,0.004976656,0.04164016,0.9151927,0.001520313,0.0287274,0.001095811],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921085,0.00005643064,0.001871471,0.0007010865,0.0001437143,0.0002043766,0.00009762337,0.00143011,0.003386702],"genre_scores_gemma":[0.8591574,0.00001445706,0.0002784794,0.00003418889,0.0003074326,0.0001692492,0.0004602499,0.00008311417,0.1394954],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1361087,"threshold_uncertainty_score":0.9734523,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04302117764189643,"score_gpt":0.3229577129636706,"score_spread":0.2799365353217741,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}