{"id":"W4362611283","doi":"10.1021/acscatal.2c03828","title":"Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)","year":2023,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Universitetet i Bergen; Norges Forskningsråd; University of Ottawa","keywords":"Carbene; Catalysis; Ruthenium; Olefin metathesis; Alkyl; Chemistry; Acyclic diene metathesis; Metathesis; Olefin fiber; Medicinal chemistry; Photochemistry; Combinatorial chemistry; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008164279,0.000157724,0.0001461866,0.0001161434,0.00008929909,0.0002521928,0.0003091838,0.0002000055,0.003116479],"category_scores_gemma":[0.0001674211,0.0001361612,0.0001428938,0.0001022037,0.0001139462,0.0001545195,0.0001103646,0.0002685781,0.0002546498],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003684566,"about_ca_system_score_gemma":0.0001476176,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001216418,"about_ca_topic_score_gemma":0.001389019,"domain_scores_codex":[0.9999627,0.000002901769,0.000001481621,0.000008901551,0.00001229342,0.00001185774],"domain_scores_gemma":[0.9999565,0.00001811385,0.00001082626,0.000004075468,0.000005417494,0.000005108092],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005930645,0.0001301999,0.001142479,0.0002618165,0.00001935905,0.0001418848,0.00007246906,0.03759622,0.9483858,0.002417507,0.0006044563,0.00863477],"study_design_scores_gemma":[0.00006035901,0.0004652471,0.001995328,0.000008421579,0.00001495182,0.00002643204,0.0000424369,0.1332576,0.8621133,0.0002500161,0.001752804,0.00001321828],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947248,0.0001498937,0.001717713,0.00002960027,0.000006979908,0.000008476934,0.0001780268,0.0001396047,0.003044866],"genre_scores_gemma":[0.9983553,0.00006936355,0.0009451971,0.000002356986,9.742846e-7,0.000009303435,0.00009979896,0.00001261057,0.0005049196],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003116479,"threshold_uncertainty_score":0.01042569,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03487362108611553,"score_gpt":0.2937325695114332,"score_spread":0.2588589484253176,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}