{"id":"W4362692895","doi":"10.1021/acs.jpcb.3c00583","title":"Extraordinary Control of Photosensitized Singlet Oxygen Generation by Acyclic Cucurbituril-like Containers","year":2023,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Agencia Nacional de Investigación y Desarrollo","keywords":"Singlet oxygen; Cucurbituril; Chemistry; Photochemistry; Supramolecular chemistry; Photosensitizer; Singlet fission; Singlet state; Excited state; Oxygen; Triplet state; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001074815,0.0002756387,0.0001287716,0.0001429205,0.0001156392,0.0002759494,0.0001964425,0.0001687969,0.0006120527],"category_scores_gemma":[0.0001943117,0.0001166827,0.00009587468,0.000164472,0.0001973421,0.0003263515,0.0002527023,0.0002507814,0.0001661599],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003067197,"about_ca_system_score_gemma":0.0001302632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006002377,"about_ca_topic_score_gemma":0.0008921666,"domain_scores_codex":[0.9999114,0.00001527581,0.000008280402,0.00002443602,0.00001496025,0.00002561097],"domain_scores_gemma":[0.9998686,0.00001617794,0.00005751253,0.00001274309,0.00001494989,0.00002993475],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000913446,0.00001483872,0.0001170035,0.00005302419,0.000004758856,0.00005972436,0.00004462939,0.000431082,0.9970124,0.0005847211,0.00008282391,0.001503619],"study_design_scores_gemma":[0.00000731436,0.0002083927,0.0005855251,0.000005144347,0.00001100354,0.00005811294,0.00001806002,0.001827883,0.9939418,0.00003273449,0.003292217,0.00001168411],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949788,0.0005590639,0.002497242,0.00003952048,0.00001395702,0.00001895201,0.0001142302,0.0001370882,0.001641067],"genre_scores_gemma":[0.9963951,0.0003205207,0.002241706,0.0000192779,0.000005394124,0.00001805886,0.000109678,0.00002671626,0.0008636374],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006120527,"threshold_uncertainty_score":0.002225459,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01261460706715468,"score_gpt":0.2369224678002993,"score_spread":0.2243078607331446,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}