{"id":"W4365147219","doi":"10.1515/iupac.94.0593","title":"Isotope Effect, Intramolecular","year":2023,"lang":"en","type":"dataset","venue":"IUPAC Standards Online","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Glossary; Terminology; Abandonment (legal); Meaning (existential); Intramolecular force; Field (mathematics); Chemistry; Computer science; Epistemology; Linguistics; Philosophy; Mathematics; Organic chemistry; Political science; Pure mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["research_integrity"],"category_scores_codex":[0.001068933,0.0006185297,0.0008448187,0.0002551481,0.0002424367,0.00006083215,0.0006201135,0.00134065,0.005147598],"category_scores_gemma":[0.001339654,0.0005440595,0.0003541856,0.0005022258,0.0002761458,0.00006409839,0.0003044175,0.002910241,0.0002460766],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003909821,"about_ca_system_score_gemma":0.0004102282,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002530214,"about_ca_topic_score_gemma":0.0002906735,"domain_scores_codex":[0.9970003,0.0003654411,0.0005778194,0.0006769286,0.0006502882,0.0007291778],"domain_scores_gemma":[0.9976932,0.0007330187,0.0002296845,0.0006515043,0.000274798,0.0004178272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003980497,0.0003595162,0.00001292422,0.0002773818,0.0004212406,0.0003647133,0.000007848909,0.00001624177,0.001162819,0.00001067911,0.9886573,0.008311269],"study_design_scores_gemma":[0.001441511,0.0003865014,0.00001609004,0.0001081925,0.0005805296,0.00003387863,0.00001033068,0.00005642661,0.002790204,0.000102391,0.9939287,0.0005452931],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"dataset","genre_gemma":"dataset","genre_scores_codex":[0.002294681,0.0008821145,0.00001816834,0.0006521474,0.003208935,0.0006787287,0.9917803,0.0002654995,0.0002194686],"genre_scores_gemma":[0.00007762703,0.002901427,0.00001494369,0.001296693,0.001391627,0.0001079594,0.9930245,0.00008170715,0.00110353],"genre_candidate":"dataset","genre_consensus":"dataset","teacher_disagreement_score":0.007765975,"threshold_uncertainty_score":0.9999558,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04930396294640464,"score_gpt":0.5251285211222118,"score_spread":0.4758245581758071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}