{"id":"W4366974760","doi":"10.3762/bjoc.19.38","title":"Transition-metal-catalyzed domino reactions of strained bicyclic alkenes","year":2023,"lang":"en","type":"review","venue":"Beilstein Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Domino; Synthon; Stereocenter; Bicyclic molecule; Reactivity (psychology); Catalysis; Organic synthesis; Combinatorial chemistry; Transition metal; Substrate (aquarium); Cascade reaction; Scope (computer science); Organic chemistry; Nanotechnology; Computer science; Enantioselective synthesis; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001815309,0.0007023063,0.0006612253,0.001073578,0.0002097193,0.0004897948,0.0004705532,0.0004582015,0.002014066],"category_scores_gemma":[0.0001921842,0.0002724139,0.0003340973,0.0009674969,0.0001828142,0.0007703985,0.0004092106,0.0009371361,0.001202185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003336174,"about_ca_system_score_gemma":0.0003397425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004245725,"about_ca_topic_score_gemma":0.0009456195,"domain_scores_codex":[0.9999075,0.000007771619,0.000008212358,0.00002150794,0.00003096275,0.0000240184],"domain_scores_gemma":[0.9999679,0.00001187896,0.000006235474,0.000001916675,0.000007343079,0.000004675725],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0000932871,0.000141244,0.0001495845,0.02333855,0.0001375831,0.0005999187,0.000134352,0.001752225,0.07895271,0.01374489,0.01559002,0.8653656],"study_design_scores_gemma":[0.00002158487,0.0002123219,0.0005442309,0.001102235,0.00009597079,0.001274069,0.00004827993,0.0004252803,0.034607,0.001675242,0.959959,0.0000347552],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.003917577,0.9858765,0.001770674,0.000167361,0.000343314,0.00002843675,0.00008998937,0.00005954887,0.007746579],"genre_scores_gemma":[0.01985518,0.9727577,0.00161764,0.0002212638,0.0001225699,0.00003611684,0.0001240441,0.000009311716,0.005256336],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.002014066,"threshold_uncertainty_score":0.006737709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05511705741945793,"score_gpt":0.3342973012447353,"score_spread":0.2791802438252774,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}