{"id":"W4367049445","doi":"10.1021/acssuschemeng.3c00103","title":"Antioxidant Silicone Elastomers without Covalent Cross-Links","year":2023,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Elastomer; Tannic acid; Pyrogallol; Silicone; Antioxidant; Covalent bond; Vulcanization; Silicone Elastomers; Catechol; Chemistry; Polymer chemistry; Ionic bonding; Organic chemistry; Polymer science; Materials science; Chemical engineering; Natural rubber","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003965075,0.0002797304,0.0002905992,0.00007974995,0.0002339806,0.0002377983,0.0003942833,0.0001925244,0.0001283321],"category_scores_gemma":[0.0001034305,0.0003010889,0.00008571423,0.0005305033,0.00006107758,0.0002670318,0.0002725911,0.0003248684,0.0001152995],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000215662,"about_ca_system_score_gemma":0.0001009736,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007070837,"about_ca_topic_score_gemma":1.34074e-7,"domain_scores_codex":[0.9977658,0.000009168798,0.0003453507,0.0004588475,0.0003102835,0.00111054],"domain_scores_gemma":[0.999079,0.00006816317,0.00007881127,0.0004341783,0.000126702,0.000213159],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001255856,0.00001766757,0.0008591749,0.0006824472,0.00001458269,0.0001400681,0.000161313,0.07538161,0.9224946,0.0001363048,0.00006084727,0.00003874457],"study_design_scores_gemma":[0.0003748338,0.00001356572,0.0009678469,0.00006497587,0.00001536717,0.00003701628,0.0004039268,0.01317743,0.9764637,0.00002403176,0.008089101,0.0003681484],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964089,0.0005034931,0.0009855224,0.00008930451,0.0002185474,0.000137374,0.00001140038,0.0008682053,0.0007771957],"genre_scores_gemma":[0.9928423,0.00006810998,0.0003799608,0.00003214257,0.0002087099,0.0000414907,0.00002560962,0.00006004129,0.006341625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06220419,"threshold_uncertainty_score":0.9999442,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006302067990038671,"score_gpt":0.2359236879805041,"score_spread":0.2296216199904654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}