{"id":"W4367172367","doi":"10.1021/jacs.3c02256","title":"Cationic Phosphinidene as a Versatile P<sub>1</sub> Building Block: [L<sub>C</sub>–P]<sup>+</sup> Transfer from Phosphonio–Phosphanides [L<sub>C</sub>–P–PR<sub>3</sub>]<sup>+</sup> and Subsequent L<sub>C</sub> Replacement Reactions (L<sub>C</sub> = N-Heterocyclic Carbene)","year":2023,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Fonds der Chemischen Industrie; Natural Sciences and Engineering Research Council of Canada; Deutscher Akademischer Austauschdienst; Agencia Estatal de Investigación; Technische Universität Dresden; European Regional Development Fund; Deutsche Forschungsgemeinschaft","keywords":"Cationic polymerization; Chemistry; Reagent; Phosphinidene; Nucleophile; Aryl; Medicinal chemistry; Substituent; Stereochemistry; Electrophile; Wittig reaction; Alkyl; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008513589,0.0004718218,0.0001693066,0.0001099338,0.0001564541,0.0003095306,0.0004133064,0.0003710922,0.001682762],"category_scores_gemma":[0.0001184424,0.0001684946,0.0001514154,0.0001630357,0.0002060868,0.0003629612,0.0003517897,0.0004774393,0.0007339848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002514528,"about_ca_system_score_gemma":0.0002207459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003734094,"about_ca_topic_score_gemma":0.0004004444,"domain_scores_codex":[0.9999243,0.000008295636,0.000005373804,0.00001991066,0.00001702175,0.00002512449],"domain_scores_gemma":[0.9999653,0.000003988954,0.00001199137,0.000005282172,0.000004942254,0.0000084983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001097113,0.00002685017,0.00006565479,0.0001435502,0.000007091664,0.000193398,0.00004658727,0.0003758342,0.9932592,0.001226229,0.0001937714,0.004352094],"study_design_scores_gemma":[0.00001271941,0.0001375853,0.0002127894,0.000003038808,0.000005538064,0.0001755887,0.00001157336,0.0003849891,0.9960531,0.00007207966,0.002924812,0.000006173457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9755819,0.001196127,0.0118052,0.0001579905,0.00005526411,0.0001200201,0.000352719,0.0004435917,0.01028717],"genre_scores_gemma":[0.9922727,0.0006258605,0.003445833,0.0000398577,0.0000077655,0.00004646751,0.0001952355,0.00003461527,0.003331667],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001682762,"threshold_uncertainty_score":0.005629361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01127290927429113,"score_gpt":0.2251422840127987,"score_spread":0.2138693747385076,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}