{"id":"W4367302021","doi":"10.1055/a-2083-8591","title":"Silyl Esters as Reactive Intermediates in Organic Synthesis","year":2023,"lang":"en","type":"article","venue":"Synthesis","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"","keywords":"Silylation; Chemistry; Reactivity (psychology); Aldehyde; Amine gas treating; Organic chemistry; Catalysis; Reactive intermediate; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003185602,0.00022402,0.0003116206,0.0001817868,0.000056006,0.00003423,0.0003209241,0.0001965025,0.0005998945],"category_scores_gemma":[0.002752113,0.0002046692,0.0002191774,0.0004935013,0.00009318149,0.000007062366,0.0001723291,0.00009848033,0.0005489723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000448529,"about_ca_system_score_gemma":0.00004799143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001243654,"about_ca_topic_score_gemma":0.0001401488,"domain_scores_codex":[0.9984948,0.0001004129,0.0002876824,0.0005333865,0.0001808947,0.0004028357],"domain_scores_gemma":[0.9989177,0.0004212315,0.00008592767,0.0004247716,0.00003553385,0.0001148557],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005313018,0.00006880626,0.008143403,0.00001911811,0.0001303836,0.0000211295,0.00006850815,0.000006481158,0.9713291,0.0000133026,0.0007894983,0.01935714],"study_design_scores_gemma":[0.00008971325,0.00002489241,0.0086873,0.00007046403,0.00006920108,0.000004975444,0.0005371609,0.00006087245,0.9858062,0.0001684384,0.004189918,0.0002908896],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958717,0.0001234084,0.00001406621,0.0008206521,0.00005983228,0.00009073278,0.00002056318,0.00005328727,0.002945797],"genre_scores_gemma":[0.9983475,0.0003898694,0.00006250263,0.0001098877,0.0001414059,0.0001280122,0.00002551984,0.00004555365,0.0007497827],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01906625,"threshold_uncertainty_score":0.8346166,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006272304528399121,"score_gpt":0.2374038873600577,"score_spread":0.2311315828316586,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}