{"id":"W4376118206","doi":"10.56530/lcgc.na.dd4071d9","title":"Rapid and Sensitive Determination of Residues of Triphenylmethane Dyes and Their Metabolites in Animal Tissues by LC–MS/MS","year":2023,"lang":"en","type":"article","venue":"LCGC North America","topic":"Dye analysis and toxicity","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"PerkinElmer Biosignal","funders":"","keywords":"Analyte; Triphenylmethane; Chromatography; Chemistry; Formic acid; Ammonium formate; Matrix (chemical analysis); Mass spectrometry; Sample preparation; Liquid chromatography–mass spectrometry; Calibration curve; Analytical Chemistry (journal); Detection limit; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001210799,0.0001335538,0.0004495618,0.0001167899,0.00002632958,0.00001118245,0.00006104706,0.00004836179,0.00005965259],"category_scores_gemma":[0.0001169954,0.0001115284,0.00005321094,0.0004208832,0.0001980802,0.00008705292,0.00005938897,0.00007514087,0.000001155519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000006141725,"about_ca_system_score_gemma":0.00001134802,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006839138,"about_ca_topic_score_gemma":0.0002630682,"domain_scores_codex":[0.9991494,0.00004795453,0.0002891,0.0002307376,0.0001256115,0.0001572216],"domain_scores_gemma":[0.9992978,0.0002400857,0.0002065368,0.0001461785,0.00006121024,0.00004821579],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001546302,0.0001163753,0.1713256,0.0002276704,0.0001509706,0.00001484371,0.003459613,0.000003618989,0.5108725,0.00001071716,0.0001549237,0.3135085],"study_design_scores_gemma":[0.0004202994,0.00009924102,0.1228849,0.00004279159,0.00007214375,0.000001708929,0.00138057,0.001182808,0.8713579,0.00009278665,0.002287709,0.0001771626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966963,0.002069837,0.00004034333,0.00006174178,0.000005992654,0.00004201293,0.0001844889,0.00002298011,0.0008762961],"genre_scores_gemma":[0.9972962,0.002147243,0.0002157059,0.00001843663,0.00002422355,0.000004804858,0.00008818103,0.00001076188,0.0001944598],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3604854,"threshold_uncertainty_score":0.4547995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00977892941329957,"score_gpt":0.2399032901433761,"score_spread":0.2301243607300765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}