{"id":"W4376121371","doi":"10.1002/chir.23577","title":"Chiral perturbation on single benzene‐based fluorophores: A structure/(chir)optical activity relationship study","year":2023,"lang":"en","type":"article","venue":"Chirality","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Ministère de l'Éducation et de l'Enseignement supérieur; Ministère de l'Education Nationale, de l'Enseignement Supérieur et de la Recherche","keywords":"Chemistry; Fluorophore; Luminescence; Benzene; Moiety; Phthalonitrile; Photochemistry; Molecule; Toluene; Acceptor; Fluorescence; Crystallography; Stereochemistry; Organic chemistry; Optoelectronics; Phthalocyanine; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001503855,0.0001584314,0.0001361998,0.0001344666,0.00008978801,0.0001856025,0.000150838,0.0001303162,0.001031248],"category_scores_gemma":[0.0002012093,0.00008156101,0.00008814056,0.0001202108,0.0001672284,0.0002113426,0.00008694664,0.0002501262,0.0001978057],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00024241,"about_ca_system_score_gemma":0.00008177673,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003876213,"about_ca_topic_score_gemma":0.0004255153,"domain_scores_codex":[0.9999326,0.00001308922,0.000001945258,0.00001346395,0.00002333655,0.00001547426],"domain_scores_gemma":[0.9998568,0.00005020614,0.00004416779,0.00001119616,0.00002251234,0.00001502308],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002524877,0.00001682328,0.0001518124,0.00001393665,0.000001981869,0.0000252779,0.000007959612,0.000133506,0.9977963,0.0001127274,0.00001357045,0.001700967],"study_design_scores_gemma":[0.000002686844,0.00007431846,0.0005971412,0.000001314746,0.000003570386,0.00005759471,0.000003898623,0.001435395,0.9974812,0.00001608499,0.000325419,0.000001405144],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993008,0.001197969,0.004058287,0.00003825218,0.000005527771,0.000008666088,0.00004599056,0.000037932,0.00159926],"genre_scores_gemma":[0.9969916,0.0004230172,0.002003442,0.00001280482,0.000004283598,0.000004120942,0.00003839568,0.000005994152,0.0005163412],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001031248,"threshold_uncertainty_score":0.003449857,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0750524998343802,"score_gpt":0.2818696974388554,"score_spread":0.2068171976044752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}