{"id":"W4376134270","doi":"10.1021/acsorginorgau.3c00010","title":"Nickel Complexes of Allyl and Vinyldiphenylphosphine","year":2023,"lang":"en","type":"article","venue":"ACS Organic & Inorganic Au","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund; Carnegie Trust for the Universities of Scotland; Canada Foundation for Innovation; Council of Ontario Universities; University of Windsor","keywords":"Phosphine; Chemistry; Olefin fiber; Denticity; Reactivity (psychology); Nickel; Diphenylphosphine; Cyclooctadiene; Ring (chemistry); Catalysis; Medicinal chemistry; Photochemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005288395,0.0002200264,0.0001368479,0.0001283349,0.0001407036,0.000419869,0.000421596,0.0002555684,0.003603629],"category_scores_gemma":[0.0001288009,0.0001410028,0.00008406519,0.00009892031,0.0001476928,0.0002374527,0.0002432978,0.0002987176,0.0004335358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004655988,"about_ca_system_score_gemma":0.0001104493,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000855802,"about_ca_topic_score_gemma":0.001136039,"domain_scores_codex":[0.9999043,0.000009398386,0.000004052447,0.00002872422,0.00002874258,0.0000248382],"domain_scores_gemma":[0.9999765,0.000004807793,0.000006590793,0.000003595429,0.000003063168,0.000005440301],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003325352,0.00002547476,0.0002571898,0.0001799479,0.00002073637,0.0001689213,0.0001009984,0.0005936479,0.9880928,0.003265189,0.0008757068,0.006086832],"study_design_scores_gemma":[0.00001690343,0.00009955867,0.0006351336,0.000006833323,0.000007228283,0.000138379,0.00004751574,0.002293044,0.9897827,0.0002016443,0.00676461,0.000006506153],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9632847,0.001452044,0.003186886,0.0001691375,0.0000518934,0.00001879866,0.0002628118,0.0002889031,0.03128482],"genre_scores_gemma":[0.9920788,0.0002999775,0.000850552,0.00002134648,0.000004549634,0.000009874897,0.0002260407,0.00002259759,0.006486265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003603629,"threshold_uncertainty_score":0.0120554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01081520860897149,"score_gpt":0.2295788370695888,"score_spread":0.2187636284606173,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}