{"id":"W4376143460","doi":"10.26434/chemrxiv-2023-hc0g0","title":"Divergent Stabilities of Tetravalent Cerium, Uranium, and Neptunium Imidophosphorane Complexes","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Office of Science; Basic Energy Sciences; University of Akron; Canadian Centre for Applied Research in Cancer Control; New Mexico State University; U.S. Department of Energy","keywords":"Cerium; Neptunium; Homoleptic; Redox; Chemistry; Actinide; Lanthanide; Oxidation state; Inorganic chemistry; Ligand (biochemistry); Density functional theory; Aqueous solution; Electrochemistry; Metal; Crystallography; Computational chemistry; Ion; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001214135,0.0001511552,0.0001720097,0.0001771089,0.0001987947,0.0003956812,0.0005381766,0.000262535,0.001118079],"category_scores_gemma":[0.0003285091,0.000129694,0.00008703805,0.0001585668,0.0002805679,0.0002102456,0.0003182752,0.0003454569,0.0001342585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003852469,"about_ca_system_score_gemma":0.0001329909,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006979755,"about_ca_topic_score_gemma":0.000764209,"domain_scores_codex":[0.9998868,0.00001445339,0.000007109646,0.00003160091,0.00003851514,0.00002148853],"domain_scores_gemma":[0.9999542,0.00001507903,0.000011232,0.000004334072,0.000008593134,0.000006528029],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002277536,0.00001975734,0.0004935682,0.0001535708,0.00001636043,0.00008700987,0.0001833177,0.0007327521,0.9906675,0.002677229,0.0001532176,0.004587799],"study_design_scores_gemma":[0.00001302667,0.0001039057,0.001123207,0.000008106264,0.000008467975,0.0001289615,0.00008020565,0.004615888,0.9912223,0.0003332063,0.002353293,0.000009403367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950622,0.0006799262,0.001444862,0.0000551062,0.000008938228,0.000006111658,0.00009207128,0.00003705595,0.00261384],"genre_scores_gemma":[0.9981269,0.0002517473,0.0006817326,0.00001399459,0.000001925516,0.000009334718,0.00015462,0.00001111829,0.0007486386],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001118079,"threshold_uncertainty_score":0.00374037,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04307987172029878,"score_gpt":0.2686113534750688,"score_spread":0.22553148175477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}