{"id":"W4377820038","doi":"10.1002/ange.202304964","title":"Sterically‐Hindered Molecular p‐Dopants Promote Integer Charge Transfer in Organic Semiconductors","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique; Concordia University","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; University of Toronto; Government of Canada; Concordia University; Fonds de recherche du Québec – Nature et technologies; Canadian Light Source","keywords":"Dopant; Steric effects; Organic semiconductor; Chemistry; Electron transfer; Doping; Semiconductor; Computational chemistry; Materials science; Molecule; Chemical physics; Photochemistry; Organic chemistry; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009095449,0.0002503371,0.0001049833,0.0000842076,0.0001066394,0.0002100831,0.0001200232,0.0001474831,0.0006658945],"category_scores_gemma":[0.00009118914,0.00009268121,0.00006937422,0.00006988403,0.0001658252,0.0001460222,0.0001140262,0.0001656711,0.0002383023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001513876,"about_ca_system_score_gemma":0.0001546342,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003988897,"about_ca_topic_score_gemma":0.0009036684,"domain_scores_codex":[0.9999385,0.00001200271,0.000004136123,0.00001170517,0.0000135636,0.00001999852],"domain_scores_gemma":[0.9999573,0.0000106047,0.00001412503,0.000003299923,0.000006137607,0.000008673013],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003850688,0.00001302698,0.0000685582,0.00002918148,0.000002254369,0.0000427863,0.000008136275,0.0001909217,0.9981528,0.0003672818,0.00005145669,0.001035083],"study_design_scores_gemma":[0.000007890158,0.000119329,0.0002316082,0.000002013197,0.00000276653,0.00005142052,0.000006267529,0.0009783689,0.9978383,0.0000313709,0.0007281806,0.000002605926],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936727,0.0005336012,0.003513588,0.00005331096,0.00001381602,0.00001155998,0.00006032667,0.00005772404,0.002083217],"genre_scores_gemma":[0.997525,0.0002373661,0.001561951,0.00001933548,0.000004430276,0.000006657948,0.00003727993,0.000008421477,0.0005994497],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006658945,"threshold_uncertainty_score":0.002227664,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01207032024795905,"score_gpt":0.212359578920008,"score_spread":0.200289258672049,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}