{"id":"W4378674315","doi":"10.26434/chemrxiv-2023-nc765","title":"Aqueous-phase autoxidation in the atmosphere: fate and formation of organic peroxides","year":2023,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Air Quality Monitoring and Forecasting","field":"Environmental Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Autoxidation; Chemistry; Aqueous solution; Aqueous two-phase system; Photochemistry; Environmental chemistry; NOx; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002076703,0.0003076606,0.0001553059,0.0001805766,0.0001440045,0.0003156764,0.0001301983,0.0002617285,0.00112532],"category_scores_gemma":[0.0001654564,0.00009529071,0.000165308,0.0001983979,0.0001499865,0.0003387863,0.0001693755,0.0003916957,0.0003027052],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001526733,"about_ca_system_score_gemma":0.0001179671,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006883508,"about_ca_topic_score_gemma":0.0004865459,"domain_scores_codex":[0.9999039,0.00001043649,0.000004305684,0.00003646975,0.00002334612,0.00002155143],"domain_scores_gemma":[0.9999334,0.00001620701,0.00001829889,0.000008648819,0.00001625694,0.000007187506],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004694107,0.00001879908,0.001349158,0.00008437355,0.000009253424,0.00004031916,0.00002780143,0.0002162597,0.9949129,0.0001144025,0.00005604652,0.003123807],"study_design_scores_gemma":[0.000003799745,0.00005508249,0.004149152,0.000005674724,0.00000678541,0.00004807831,0.00002579113,0.001178244,0.9928002,0.0001281675,0.001595373,0.000003660018],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.984264,0.003806959,0.009429623,0.0000817641,0.00003942415,0.000035958,0.0006968306,0.00007807642,0.001567438],"genre_scores_gemma":[0.9890547,0.002156992,0.005951364,0.00003667967,0.00001883385,0.00002165693,0.0008271709,0.00002951936,0.001903028],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00112532,"threshold_uncertainty_score":0.00376451,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05066480858693441,"score_gpt":0.2907447117334396,"score_spread":0.2400799031465052,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}