{"id":"W4378745528","doi":"10.1002/chem.202301063","title":"Direct Alkylative Amination Using 1‐Allylsilatrane**","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Toronto Metropolitan University; University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Amination; Aniline; Imine; Chemistry; Aldehyde; Reductive amination; Catalysis; Organic chemistry; Metal; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002919554,0.0009011543,0.000306767,0.0002788709,0.0002372321,0.0002010341,0.0004805855,0.0003684684,0.003050431],"category_scores_gemma":[0.0003068946,0.0002217358,0.0002103746,0.0002455607,0.0001931765,0.0004224068,0.0004544012,0.0006378511,0.001801573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002402745,"about_ca_system_score_gemma":0.0002721435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003244464,"about_ca_topic_score_gemma":0.001352099,"domain_scores_codex":[0.9998067,0.00002867815,0.00001958048,0.00004697462,0.0000326404,0.00006549173],"domain_scores_gemma":[0.9997917,0.00005202038,0.00005981608,0.00003524507,0.00003206674,0.00002920061],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007803899,0.00004349314,0.000162076,0.0002305562,0.00002043348,0.0002355416,0.00007665273,0.0001551773,0.9911583,0.0005926829,0.0002048348,0.007042289],"study_design_scores_gemma":[0.000005849264,0.0001562373,0.0004598234,0.000005544377,0.000006770753,0.0001822223,0.00001109491,0.0001752745,0.9956547,0.00004359398,0.003292831,0.000006190073],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9379389,0.004440803,0.0223469,0.0003080537,0.0002351196,0.000218214,0.000938085,0.0004342137,0.0331397],"genre_scores_gemma":[0.9787718,0.003155483,0.01001956,0.00007803209,0.00003879319,0.00007947119,0.0006610997,0.0000718215,0.007123908],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003050431,"threshold_uncertainty_score":0.01020467,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04364522436351281,"score_gpt":0.2911625512870927,"score_spread":0.2475173269235799,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}