{"id":"W4379599281","doi":"10.1002/anie.202306447","title":"Bismuth‐Catalyzed Amide Reduction","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"HORIZON EUROPE European Research Council; Engineering and Physical Sciences Research Council; Max-Planck-Gesellschaft; Natural Sciences and Engineering Research Council of Canada; University of Manchester; Verband der Chemischen Industrie","keywords":"Bismuth; Reduction (mathematics); Catalysis; Amide; Chemistry; Organic chemistry; Mathematics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000158949,0.0006272078,0.0002020223,0.0003553502,0.0002231781,0.0002771285,0.0005870297,0.0003809391,0.002678615],"category_scores_gemma":[0.0001436864,0.0002697012,0.000222101,0.0001883129,0.0001797393,0.0003377514,0.0004182607,0.0005258745,0.001927434],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003447247,"about_ca_system_score_gemma":0.0002085281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002901526,"about_ca_topic_score_gemma":0.0005031809,"domain_scores_codex":[0.9997389,0.00002224159,0.00002058961,0.00004873694,0.0001152238,0.00005427777],"domain_scores_gemma":[0.9999604,0.000004178004,0.00001283332,0.000004764764,0.000008980831,0.000008812772],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006748889,0.00003976752,0.0001018477,0.00009042594,0.00001655908,0.00009486812,0.00002373456,0.0001009814,0.9903656,0.001224014,0.0006572548,0.007217365],"study_design_scores_gemma":[0.00000766779,0.00005711866,0.0001662098,0.000003623472,0.000007547817,0.0001656333,0.000004698526,0.0003474681,0.9901444,0.0001039269,0.008986523,0.000005175339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8646437,0.004198032,0.06234389,0.0005161974,0.0005787304,0.00039424,0.001698204,0.003718146,0.06190887],"genre_scores_gemma":[0.9659277,0.001389601,0.01366666,0.000104436,0.00004135925,0.0001065782,0.001282707,0.0001818553,0.01729902],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002678615,"threshold_uncertainty_score":0.008960843,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01695421231029787,"score_gpt":0.2646085419398967,"score_spread":0.2476543296295988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}