{"id":"W4379619018","doi":"10.1002/ange.202306447","title":"Bismuth‐Catalyzed Amide Reduction","year":2023,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Max-Planck-Gesellschaft; HORIZON EUROPE European Research Council; Natural Sciences and Engineering Research Council of Canada; University of Manchester; Verband der Chemischen Industrie","keywords":"Chemistry; Nitrile; Catalysis; Amide; Alkene; Hydride; Furan; Silane; Cationic polymerization; Combinatorial chemistry; Bismuth; Aryl; Reaction mechanism; Organic chemistry; Medicinal chemistry; Metal; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001466518,0.0003288268,0.0001695981,0.0001354221,0.0001495251,0.0002497566,0.0003510535,0.0002140299,0.001168835],"category_scores_gemma":[0.0001212304,0.0001004294,0.0001310178,0.00008424938,0.0001439157,0.0002936253,0.0003125815,0.0004164935,0.0005759263],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000196017,"about_ca_system_score_gemma":0.000126129,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003112739,"about_ca_topic_score_gemma":0.00038803,"domain_scores_codex":[0.9998254,0.00002639778,0.00001196305,0.00002954993,0.0000719156,0.0000348848],"domain_scores_gemma":[0.9999577,0.000005379024,0.000009944714,0.000004829908,0.00001150014,0.00001073624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003285941,0.00001500612,0.00003661595,0.00004027409,0.000006482026,0.00004352608,0.00002321413,0.00005248516,0.9972671,0.0004078835,0.00006850913,0.002005995],"study_design_scores_gemma":[0.000005422357,0.00005666096,0.0001574725,0.000001875121,0.000005586292,0.00009762501,0.000006074061,0.0003848567,0.9961538,0.00005076504,0.00307563,0.00000423338],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9526345,0.002765279,0.02660994,0.0002074964,0.0002498218,0.00006474297,0.0001340806,0.0003222346,0.01701178],"genre_scores_gemma":[0.9889243,0.0006778467,0.004616156,0.00003912824,0.00001978376,0.00001324635,0.0001274686,0.00003772923,0.005544342],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001168835,"threshold_uncertainty_score":0.003910184,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01980258250078078,"score_gpt":0.2538266023786852,"score_spread":0.2340240198779044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}