{"id":"W4380422419","doi":"10.1002/chem.202301640","title":"Formal Synthesis of (±)‐Salvinorin A via Gold(I) Catalysis","year":2023,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; iCo Therapeutics (Canada); FPInnovations","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Combinatorial chemistry; Chemistry; Nanotechnology; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007282692,0.0002948006,0.0004159165,0.00005431192,0.0001548321,0.00008292368,0.0007729465,0.00007914974,0.005656623],"category_scores_gemma":[0.0004559514,0.0002668446,0.0004821938,0.0003267235,0.0001395135,0.0001596136,0.0002890514,0.0005248334,0.0003461758],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008168111,"about_ca_system_score_gemma":0.00004886844,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004383744,"about_ca_topic_score_gemma":1.473343e-7,"domain_scores_codex":[0.9978023,0.00004482662,0.0007576742,0.0003284404,0.0004522119,0.0006146063],"domain_scores_gemma":[0.998409,0.0002118039,0.0004048155,0.0005125676,0.00009415527,0.0003677042],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003669464,0.00008766804,0.0004235934,0.0003023117,0.0001322188,0.0002585834,0.00007867227,0.00001494409,0.945228,0.000001537107,0.003512377,0.04992339],"study_design_scores_gemma":[0.0003891346,0.00000740266,0.0002811994,0.000270557,0.0001057728,0.0003930459,0.0002570219,0.0006074953,0.9845101,0.00003239249,0.01281873,0.000327155],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9110548,0.0001170278,0.00006582397,0.0001221135,0.00004172904,0.00001651191,0.00003765262,0.0001476457,0.08839674],"genre_scores_gemma":[0.9931597,0.0001296645,0.000167523,0.00001564299,0.0007721024,0.000004792901,0.00003006472,0.00007833266,0.005642203],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08275453,"threshold_uncertainty_score":0.9999784,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0115983762966471,"score_gpt":0.2070758008256448,"score_spread":0.1954774245289977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}