{"id":"W4380870945","doi":"10.1063/5.0139090","title":"High-order pump–probe and high-order two-dimensional electronic spectroscopy on the example of squaraine oligomers","year":2023,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Stiftung Begabtenförderung Cusanuswerk; Deutsche Forschungsgemeinschaft; Alexander von Humboldt-Stiftung","keywords":"Spectroscopy; Coherence (philosophical gambling strategy); Excitation; Coherent spectroscopy; SIGNAL (programming language); Electric field; Chemistry; Polarization (electrochemistry); Physics; Field (mathematics); Computational physics; Atomic physics; Optics; Quantum mechanics; Computer science; Mathematics; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002454146,0.0003379609,0.0001763865,0.0003854693,0.0003102778,0.0004144982,0.0003077756,0.0006299143,0.0014305],"category_scores_gemma":[0.0005061144,0.0001755372,0.0001805663,0.0003747379,0.0008126984,0.0008680348,0.0004414395,0.0007396414,0.0002164652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003085198,"about_ca_system_score_gemma":0.0001368216,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003089239,"about_ca_topic_score_gemma":0.0004189951,"domain_scores_codex":[0.999804,0.00005264025,0.000006717408,0.00005659633,0.00005900811,0.00002114514],"domain_scores_gemma":[0.9997814,0.00008175867,0.00004423406,0.00005548072,0.00002148751,0.00001563487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009632,0.0000524091,0.0005573317,0.0001415668,0.00001302682,0.0004038358,0.0004296318,0.004074472,0.8809713,0.102122,0.0002906197,0.01084753],"study_design_scores_gemma":[0.00002641874,0.0003737014,0.003607672,0.00007705105,0.00002093112,0.0009208941,0.0001364332,0.1290891,0.7986868,0.05187817,0.0151015,0.00008140744],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8380624,0.001635398,0.1359718,0.0007289354,0.0001136652,0.00005439766,0.0002335741,0.0004559767,0.02274392],"genre_scores_gemma":[0.9492933,0.0005737038,0.04748493,0.0001154023,0.00003684575,0.0000404734,0.00007900658,0.00004901094,0.002327266],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0014305,"threshold_uncertainty_score":0.004785538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0128832117533196,"score_gpt":0.2539397448055625,"score_spread":0.2410565330522429,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}