{"id":"W4381510522","doi":"10.1007/s10953-023-01281-4","title":"First Ionization Constant of Phosphoric Acid and of Acetic Acid in H2O and D2O from T = 373 K to 573 K at p = 11.5 and 20 MPa by AC Conductivity Methods","year":2023,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Chemical and Physical Properties in Aqueous Solutions","field":"Chemical Engineering","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Phosphoric acid; Hydrochloric acid; Acid dissociation constant; Molar conductivity; Inorganic chemistry; Aqueous solution; Sodium hydroxide; Sodium; Potassium; Potentiometric titration; Acetic acid; Analytical Chemistry (journal); Chloride; Potassium hydroxide; Chromatography; Physical chemistry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004111334,0.0006173368,0.0003030653,0.001104394,0.0007490188,0.0004452946,0.0009241288,0.0004065626,0.009568239],"category_scores_gemma":[0.0009299678,0.0003778736,0.0002770369,0.001036786,0.0007483755,0.0008283427,0.0004540594,0.001228442,0.0009512936],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009144507,"about_ca_system_score_gemma":0.0007245016,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006583223,"about_ca_topic_score_gemma":0.006833767,"domain_scores_codex":[0.9997748,0.00001792193,0.00001072466,0.0000665389,0.00007195525,0.00005808882],"domain_scores_gemma":[0.9996529,0.0001557082,0.00004716903,0.00003587835,0.00008853957,0.00001976797],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005025066,0.00001941585,0.000765887,0.0002971852,0.00002374981,0.0001347316,0.0004915012,0.000790839,0.985289,0.002623813,0.0009473645,0.008114045],"study_design_scores_gemma":[0.00003898075,0.00009362774,0.004828826,0.00003018341,0.00002358282,0.0001566587,0.0001929171,0.002290387,0.9865372,0.0007587374,0.005010892,0.00003799516],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9520338,0.0042766,0.01491459,0.0005890329,0.0001273793,0.00006782938,0.003305124,0.0006901153,0.02399556],"genre_scores_gemma":[0.9894719,0.001361476,0.002914777,0.00005164113,0.00001553225,0.00005593187,0.0008537161,0.0001078391,0.005167081],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009568239,"threshold_uncertainty_score":0.03200895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01817992337055257,"score_gpt":0.2682224664841324,"score_spread":0.2500425431135799,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}