{"id":"W4381890053","doi":"10.1149/1945-7111/ace0dc","title":"Synthesis of α-Amino Acids via Electrochemical Fixation of CO<sub>2</sub> to Imines Using Different Metal Cathodes","year":2023,"lang":"en","type":"article","venue":"Journal of The Electrochemical Society","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Electrochemistry; Selectivity; Faraday efficiency; Catalysis; Carbon fixation; Cathode; Amino acid; Metal; Chemistry; Materials science; Inorganic chemistry; Combinatorial chemistry; Organic chemistry; Electrode; Carbon dioxide; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001179119,0.0004736301,0.0003028868,0.0002428794,0.0001448491,0.0002475338,0.0003724821,0.0003908939,0.0005185189],"category_scores_gemma":[0.000215866,0.0001818887,0.0001880623,0.0002144487,0.0001662655,0.0002976839,0.0001949059,0.0002733691,0.0003031259],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002659266,"about_ca_system_score_gemma":0.0001366863,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004827736,"about_ca_topic_score_gemma":0.001017047,"domain_scores_codex":[0.9999049,0.000009134323,0.00001007168,0.00003003573,0.00002995731,0.00001597202],"domain_scores_gemma":[0.999934,0.00001068426,0.00001980221,0.000006432418,0.00001925291,0.000009836518],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002113072,0.000004133571,0.00003627242,0.00005303444,0.000005099501,0.00003076825,0.000008884372,0.0000901711,0.9980252,0.00005430873,0.00001355085,0.001657502],"study_design_scores_gemma":[0.000001897992,0.00002566521,0.000128304,0.000001596251,0.000003805806,0.00003397365,0.000004564328,0.0002775932,0.9990222,0.000008593252,0.0004902978,0.000001430448],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9711652,0.003483505,0.02045369,0.00009091203,0.00008573837,0.00006861804,0.0001980206,0.0002116693,0.004242464],"genre_scores_gemma":[0.9729003,0.002065488,0.02199715,0.00003638157,0.00001483933,0.00003293688,0.0001387122,0.00005007955,0.002764142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005185189,"threshold_uncertainty_score":0.001929462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01311370065325221,"score_gpt":0.2506257174825792,"score_spread":0.237512016829327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}