{"id":"W4382343833","doi":"10.1021/acs.jpca.3c02436","title":"High-Temperature Reaction Kinetics of the eaq–and HO2•Radicals with Iron(II) Ions in Aqueous Solutions","year":2023,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nuclear Laboratories","funders":"Laboratory Directed Research and Development; Atomic Energy of Canada Limited","keywords":"Radiolysis; Chemistry; Arrhenius equation; Aqueous solution; Radical; Kinetics; Chemical kinetics; Adduct; Ion; Solvated electron; Radiation chemistry; Chemical reaction; Photochemistry; Analytical Chemistry (journal); Inorganic chemistry; Physical chemistry; Activation energy; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003584006,0.0002800251,0.0002024923,0.0001201413,0.00009423248,0.0002142086,0.0002777255,0.0003696672,0.001140535],"category_scores_gemma":[0.0004968333,0.000178463,0.0001915703,0.0001114777,0.0002539217,0.0003555347,0.0001081352,0.0005195009,0.0003517242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002888853,"about_ca_system_score_gemma":0.0001510532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005359956,"about_ca_topic_score_gemma":0.0004605699,"domain_scores_codex":[0.9998171,0.0000283256,0.00001175244,0.00005176594,0.00006044201,0.00003067282],"domain_scores_gemma":[0.9997336,0.00009955557,0.00004902374,0.00001976308,0.00008028733,0.00001775714],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001123806,0.00001415982,0.0003115201,0.00002985001,0.00000442371,0.00001760195,0.00003681691,0.0002932028,0.9974299,0.00008218415,0.00003176365,0.001636139],"study_design_scores_gemma":[0.000002705851,0.0001094869,0.0008557184,0.000001394313,0.000002941745,0.00001981687,0.000009970587,0.001525654,0.9971659,0.00002112402,0.0002815462,0.000003736838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913435,0.0004762211,0.007192758,0.00004916898,0.00001742963,0.00002360722,0.000162163,0.0001003168,0.0006349718],"genre_scores_gemma":[0.9946294,0.0003200095,0.003410243,0.00001861702,0.000004870506,0.00001985267,0.0001060321,0.00001628507,0.001474644],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001140535,"threshold_uncertainty_score":0.003815472,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006218650016429552,"score_gpt":0.2052122857327543,"score_spread":0.1989936357163248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}