{"id":"W4382365820","doi":"10.2139/ssrn.4494476","title":"Rhodium-Catalyzed Ring-Opening Reactions of Azabicyclic Alkenes with Indole Nucleophiles","year":2023,"lang":"en","type":"preprint","venue":"SSRN Electronic Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Rhodium; Nucleophile; Indole test; Catalysis; Ring (chemistry); Chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003878037,0.0005412849,0.0003209799,0.000294678,0.0002224914,0.0003247685,0.000657508,0.0004573988,0.003494768],"category_scores_gemma":[0.0002733633,0.0001973699,0.0004336836,0.0001803455,0.0002658718,0.0004924632,0.0004441019,0.0008056186,0.001576963],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003493758,"about_ca_system_score_gemma":0.0002271982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005116118,"about_ca_topic_score_gemma":0.0008156752,"domain_scores_codex":[0.9997454,0.00003754856,0.00001316671,0.00004066384,0.00004957633,0.0001136535],"domain_scores_gemma":[0.9999224,0.00002549049,0.00001367867,0.00001315192,0.000007141376,0.00001812559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004653739,0.000178039,0.0002886119,0.000521032,0.00006289525,0.000862513,0.0003485908,0.0008916004,0.9721901,0.004696796,0.001084647,0.01840974],"study_design_scores_gemma":[0.00007921958,0.0006249069,0.001512189,0.00002616506,0.00004852244,0.0005071069,0.00004904639,0.00174154,0.984655,0.0006714888,0.01004999,0.00003484191],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9441459,0.005348006,0.0107083,0.0003176458,0.0002490652,0.0000985392,0.0002986064,0.0002325157,0.03860141],"genre_scores_gemma":[0.9889559,0.001705127,0.002143861,0.00005482793,0.00004785909,0.00002227689,0.0001858296,0.00002996551,0.006854263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003494768,"threshold_uncertainty_score":0.01169115,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02837694722341229,"score_gpt":0.293115072811056,"score_spread":0.2647381255876438,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}