{"id":"W4382404815","doi":"10.1016/j.cej.2023.144458","title":"Kinetic assessment for the carburization mechanisms of tungsten trioxide in the presence of methane applied to hydrogen and syngas production","year":2023,"lang":"en","type":"article","venue":"Chemical Engineering Journal","topic":"Chemical Looping and Thermochemical Processes","field":"Engineering","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"Mitacs","keywords":"Tungsten trioxide; Syngas; Nucleation; Tungsten carbide; Methane; Tungsten; Hydrogen; Chemistry; Oxide; Transition metal; Thermodynamics; Chemical engineering; Kinetic energy; Activation energy; Materials science; Reaction mechanism; Physical chemistry; Catalysis; Metallurgy; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000298678,0.0002397845,0.0002729456,0.0002585403,0.0001396818,0.000370973,0.0003636871,0.0003215735,0.000923551],"category_scores_gemma":[0.0006621766,0.0001703832,0.0003432152,0.0002042861,0.0002126569,0.0004755983,0.00017321,0.0004143159,0.0001432876],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004485417,"about_ca_system_score_gemma":0.000282976,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002150099,"about_ca_topic_score_gemma":0.002817559,"domain_scores_codex":[0.9998404,0.00002068614,0.00001238234,0.00003207516,0.00005749785,0.0000369615],"domain_scores_gemma":[0.9997485,0.0001017643,0.00003873941,0.00002148322,0.00007008381,0.00001940386],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007362376,0.00005549399,0.001604813,0.0001554009,0.00002216144,0.0000587477,0.00006609978,0.001141434,0.9914732,0.0003628315,0.00004188994,0.004281634],"study_design_scores_gemma":[0.000008499654,0.0002913087,0.003189672,0.000005280838,0.00001943224,0.00003905421,0.00006605068,0.0103855,0.9854814,0.00005887317,0.0004464636,0.000008518627],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967511,0.0006880015,0.001780453,0.00003398876,0.0000106451,0.00001764061,0.0001083403,0.00001689836,0.000592867],"genre_scores_gemma":[0.9989132,0.0002608039,0.0004267737,0.000003650991,0.000001714324,0.000005297084,0.00007261323,0.000003329989,0.0003126732],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002150099,"threshold_uncertainty_score":0.004275203,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009668957405116464,"score_gpt":0.2252230629519001,"score_spread":0.2155541055467836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}