{"id":"W4384119879","doi":"10.1021/acs.joc.3c00708","title":"BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties","year":2023,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; University of Toronto; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Chemistry; BODIPY; Furan; Boron; Quantum yield; Nucleophile; Yield (engineering); Thiophene; Photochemistry; Singlet oxygen; Combinatorial chemistry; Computational chemistry; Organic chemistry; Oxygen; Catalysis; Fluorescence","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005947831,0.0001109432,0.0001962205,0.00001358765,0.0001433843,0.00005034031,0.0002817377,0.00004049233,0.001130753],"category_scores_gemma":[0.0001074337,0.00005483193,0.00002168805,0.00008188674,0.0001604378,0.0001087083,0.0001300602,0.00005672257,0.00008531485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003595509,"about_ca_system_score_gemma":0.00006207599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004615548,"about_ca_topic_score_gemma":0.000002247725,"domain_scores_codex":[0.9992023,0.00003580983,0.0002329965,0.00008950591,0.0002529318,0.0001865252],"domain_scores_gemma":[0.9994121,0.00006284082,0.0002034194,0.0001815263,0.00007596869,0.00006412138],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001673147,0.00001132149,0.0003457531,0.0001058681,0.00001387744,0.00002353114,0.0005420168,0.000001576114,0.9980987,3.607779e-7,0.0006313561,0.00005835624],"study_design_scores_gemma":[0.0001704929,0.00002933262,0.0005793491,0.0001312858,0.00006189053,0.0006734376,0.0004652152,0.000002658067,0.9975234,0.00001330793,0.0002638713,0.00008580994],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984137,0.000497794,0.000003237958,0.0008126951,0.00009521947,0.00004311487,0.00000334177,0.00002960714,0.0001012418],"genre_scores_gemma":[0.9986153,0.0004436134,0.00003563743,0.00002995834,0.000254038,0.00000166143,3.774375e-7,0.00001729875,0.0006020815],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001045438,"threshold_uncertainty_score":0.9997823,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0160262139175091,"score_gpt":0.1993267173167148,"score_spread":0.1833005033992057,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}