{"id":"W4384662509","doi":"10.1021/acs.chemmater.3c01113","title":"Controlling the Luminescence of Rare-Earth Chalcogenide Iodides <i>RE</i><sub>3</sub>(Ge<sub>1–<i>x</i></sub>Si<sub><i>x</i></sub>)<sub>2</sub>S<sub>8</sub>I (<i>RE</i> = La, Ce, and Pr) and Ce<sub>3</sub>Si<sub>2</sub>(S<sub>1–<i>y</i></sub>Se<sub><i>y</i></sub>)<sub>8</sub>I","year":2023,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Crystal Structures and Properties","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada; Alberta Innovates; Canada First Research Excellence Fund; Canada Research Chairs; Canada Foundation for Innovation; University of Saskatchewan","keywords":"Monoclinic crystal system; Chalcogenide; Photoluminescence; Crystallography; Luminescence; Crystal structure; Materials science; Powder diffraction; Chromaticity; Phosphor; Quenching (fluorescence); Band gap; Chemistry; Physics; Fluorescence; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001369682,0.0003132143,0.0001650906,0.0001099019,0.0001180095,0.0003432172,0.0003371681,0.0001905622,0.001100345],"category_scores_gemma":[0.0002349079,0.000180983,0.0001581865,0.000143036,0.0002871513,0.0003169777,0.0003056574,0.0003254063,0.0003262569],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005268202,"about_ca_system_score_gemma":0.0003625071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0010803,"about_ca_topic_score_gemma":0.002474442,"domain_scores_codex":[0.9998881,0.000008642879,0.000007420108,0.00002865568,0.00003464753,0.00003257421],"domain_scores_gemma":[0.9998788,0.00002988622,0.00003400573,0.000009615605,0.00003085162,0.00001690039],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000698584,0.000008085347,0.000175783,0.00004621433,0.000003338534,0.00002533262,0.00004808886,0.000188471,0.9981375,0.000226452,0.00005194536,0.001019001],"study_design_scores_gemma":[0.00001003542,0.00005165373,0.0003190674,0.00000188682,0.000003507145,0.00001889414,0.00002036765,0.001022243,0.9977507,0.00002092995,0.0007776453,0.000003171482],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938344,0.0003055144,0.00260534,0.00004073342,0.00001446668,0.00001815958,0.00006909561,0.0000988584,0.00301346],"genre_scores_gemma":[0.9958503,0.0002759376,0.00179141,0.00002240151,0.000003173546,0.00002058395,0.00006428416,0.00005381767,0.001917971],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001100345,"threshold_uncertainty_score":0.003822327,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0137365263908444,"score_gpt":0.2151758036196884,"score_spread":0.2014392772288439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}