{"id":"W4384662509","doi":"10.1021/acs.chemmater.3c01113","title":"Controlling the Luminescence of Rare-Earth Chalcogenide Iodides <i>RE</i><sub>3</sub>(Ge<sub>1–<i>x</i></sub>Si<sub><i>x</i></sub>)<sub>2</sub>S<sub>8</sub>I (<i>RE</i> = La, Ce, and Pr) and Ce<sub>3</sub>Si<sub>2</sub>(S<sub>1–<i>y</i></sub>Se<sub><i>y</i></sub>)<sub>8</sub>I","year":2023,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Crystal Structures and Properties","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada; Alberta Innovates; Canada First Research Excellence Fund; Canada Research Chairs; Canada Foundation for Innovation; University of Saskatchewan","keywords":"Monoclinic crystal system; Chalcogenide; Photoluminescence; Crystallography; Luminescence; Crystal structure; Materials science; Powder diffraction; Chromaticity; Phosphor; Quenching (fluorescence); Band gap; Chemistry; Physics; Fluorescence; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.01274645,0.01125803,0.01327371,0.002280912,0.005680405,0.005590697,0.008596011,0.006506595,0.0002323277],"category_scores_gemma":[0.004560499,0.01103352,0.004350806,0.006280872,0.009743369,0.005307486,0.007083656,0.005688731,0.001274817],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001630049,"about_ca_system_score_gemma":0.003477432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003136878,"about_ca_topic_score_gemma":0.001126072,"domain_scores_codex":[0.9479279,0.004552539,0.01356112,0.01246168,0.009088843,0.01240793],"domain_scores_gemma":[0.9656192,0.005015365,0.01054964,0.009504051,0.003937708,0.005374044],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.007399329,0.001749282,0.0006865414,0.009349711,0.002053479,0.001402356,0.003304974,0.001044791,0.9436373,0.0001623164,0.01457828,0.01463169],"study_design_scores_gemma":[0.01366823,0.001540203,0.002338992,0.005520258,0.00328277,0.002349845,0.002314168,0.0004672022,0.9519901,0.002320919,0.003021773,0.01118552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9576561,0.008892209,0.0002796681,0.001973677,0.007203808,0.008968526,0.01084521,0.003349416,0.0008313383],"genre_scores_gemma":[0.949729,0.03218202,0.0003434574,0.002889351,0.006249331,0.002829909,0.003018223,0.002702442,0.00005627404],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02328981,"threshold_uncertainty_score":0.9995028,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0137365263908444,"score_gpt":0.2151758036196884,"score_spread":0.2014392772288439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}