{"id":"W4385214887","doi":"10.32920/23736735","title":"Modeling of ethylene copolymerization in nonisothermal high-pressure reactors using bifunctional initiators","year":2023,"lang":"en","type":"preprint","venue":"","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University; Natural Sciences and Engineering Research Council of Canada","funders":"","keywords":"Bifunctional; Polymerization; Copolymer; Monomer; Polymer; Peroxide; Ethylene; Polymer chemistry; Materials science; Chemical engineering; Chemistry; Thermodynamics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002034627,0.0004406014,0.0004552,0.0002025819,0.0002698203,0.0005654985,0.0005969868,0.001029682,0.001808155],"category_scores_gemma":[0.0003327248,0.0003336797,0.0006273902,0.0002340535,0.000353173,0.0005029854,0.0002080487,0.0004632428,0.0003117901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006648691,"about_ca_system_score_gemma":0.0005852394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006932888,"about_ca_topic_score_gemma":0.003108612,"domain_scores_codex":[0.9999249,0.00001607059,0.000003136496,0.00001918909,0.00001946003,0.00001727833],"domain_scores_gemma":[0.9998771,0.00007256812,0.00001954488,0.000007239776,0.00001665244,0.000006887067],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00004367663,0.00002921287,0.0002481068,0.00003895368,0.000005487796,0.00005190305,0.00001620149,0.9853905,0.01212212,0.0009955179,0.00005161291,0.001006789],"study_design_scores_gemma":[0.000005655642,0.00001735947,0.0001089443,0.00000128573,0.000002127997,0.000004898248,0.000003732971,0.9974096,0.00223298,0.0000891908,0.0001221631,0.000002052558],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8208358,0.0005717635,0.1583648,0.0002812714,0.0000415018,0.0001121502,0.0005421198,0.000316195,0.01893439],"genre_scores_gemma":[0.9830894,0.0003876434,0.009269297,0.00002433421,0.000006652901,0.0001381302,0.0001536584,0.000046161,0.006884637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006932888,"threshold_uncertainty_score":0.01378506,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04877748786935678,"score_gpt":0.2771074594686686,"score_spread":0.2283299715993118,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}