{"id":"W4385235327","doi":"10.1021/jacs.3c02103","title":"Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp<sup>2</sup>)–C(sp<sup>3</sup>) Suzuki–Miyaura Cross-Coupling","year":2023,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Bristol-Myers Squibb","keywords":"Chemistry; Transmetalation; Cobalt; Methoxide; Bromide; Electron paramagnetic resonance; Nuclear magnetic resonance spectroscopy; Catalysis; Aryl; Fluorine-19 NMR; Catalytic cycle; Sodium methoxide; Alkyl; Physical chemistry; Inorganic chemistry; Stereochemistry; Organic chemistry; Nuclear magnetic resonance","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003748471,0.0005889643,0.0003799894,0.0001199231,0.0002066754,0.0003244541,0.0005125797,0.0004533955,0.001256264],"category_scores_gemma":[0.000304216,0.0002374242,0.0002654679,0.0001139223,0.0003556701,0.0004067555,0.0003180538,0.0005785043,0.0003199202],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005431168,"about_ca_system_score_gemma":0.0002528076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00081644,"about_ca_topic_score_gemma":0.001198766,"domain_scores_codex":[0.9998443,0.00002361932,0.000008951042,0.00002335207,0.00003218424,0.00006759988],"domain_scores_gemma":[0.9998809,0.00002547466,0.0000341951,0.00001208171,0.00002232427,0.00002501416],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001781984,0.00005901812,0.0003893189,0.0002300578,0.00002736219,0.000361484,0.0001479336,0.00127357,0.9940888,0.0008407765,0.0000945948,0.002308822],"study_design_scores_gemma":[0.00001684002,0.0002373783,0.001427858,0.000007156319,0.00002032802,0.0002209579,0.00007167592,0.00275199,0.9936918,0.0001843929,0.001356497,0.00001314916],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903391,0.001481717,0.004353595,0.0001573298,0.00002168869,0.00008534714,0.0001133712,0.00008003489,0.003367809],"genre_scores_gemma":[0.997451,0.0005400319,0.001120664,0.00003710263,0.000004872017,0.00002443995,0.00006507568,0.00000681537,0.0007498881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001256264,"threshold_uncertainty_score":0.004202604,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01967268848722348,"score_gpt":0.2890235554066482,"score_spread":0.2693508669194247,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}